Author, as appears in the article.: Sanz, X.; Cascia, E.L.; Bo, C.; Whiting, A.; Fernandez, E.

Department: Química Física i Inorgànica

URV's Author/s: SANZ LÓPEZ, XAVIER; Cascia, E.L.; Bo, C.; Whiting, A.; FERNÁNDEZ GUTIÉRREZ, MARIA ELENA

Keywords: beta-boration

Abstract: The adduct [MeO ¿ Bpin-Bpin]- efficiently mediates the ¿-boration of ¿,¿-unsaturated imines formed in situ. The use of chiral phosphines as additives, and in particular the chiral phosphine (S)-MeBoPhoz, enables the catalytic asymmetric reaction to proceed with higher enantioselectivity than the analogue copper(i) mediated reaction.

Research group: Organometàl.lics i Catàlisi Homogènia

Thematic Areas: Química Química Chemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 1477-0520

Author identifier: 0000-0003-0322-6796; n/a; n/a; n/a; 0000-0001-9025-1791

Record's date: 2017-03-16

Last page: 1332

Journal volume: 13

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2015/OB/C4OB02478H#!divAbstract

Article's DOI: 10.1039/C4OB02478H

Entity: Universitat Rovira i Virgili

Journal publication year: 2015

First page: 1328

Publication Type: Article Artículo Article