Author, as appears in the article.: Fernández, E. ; La Cascia, E.; Cuenca, A.B.

Department: Química Física i Inorgànica

URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; La Cascia, E.; Cuenca, A.B.

Keywords: gem-silyborylation

Abstract: The stereocontrol on the synthesis of tetrasubstituted alkenes can be predicted by the use of gem-silaborated structures that perform selective silicon based or boron based cross-coupling reactions. Iododesilylation becomes a strategic issue to accomplish the target C-Si cross coupling. The easy access to gem-silaborated olefins, from ketones and HC(Bpin)2(SiMe3), is based on the strategic B-O olefination outcome.

Research group: Organometàl.lics i Catàlisi Homogènia

Thematic Areas: Química Química Chemistry

ISSN: 0947-6539

Author identifier: 0000-0001-9025-1791; n/a; 0000-0002-6842-1261

Record's date: 2017-03-17

Last page: 18741

Journal volume: 22

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/chem.201604782/full

Article's DOI: 10.1002/chem.201604782

Entity: Universitat Rovira i Virgili

Journal publication year: 2016

First page: 18737

Publication Type: Article Artículo Article