Author, as appears in the article.: Borrull, F. ; Salas, D. ; Fontanals, N. ; Marcé, R. M.

Department: Química Analítica i Química Orgànica

URV's Author/s: BORRULL BALLARÍN, FRANCESC; Salas, D. ; Fontanals, N. ; MARCÉ RECASENS, ROSA MARIA

Keywords: Hydrophilic interaction liquid chromatography mass spectrometry Emerging organic contaminants

Abstract: Hydrophilic interaction liquid chromatography (HILIC) has gained widespread acceptance as an alternative to reversed-phase liquid chromatography (RPLC) for the retention and separation of polar compounds. Because a great number of emerging organic contaminants are polar, this represents progress in terms of solving most of the problems and limitations encountered in the conventional methods developed for their determination. In this review, recent HILIC applications developed in the environmental field are described, which are normally coupled with mass spectrometry, in order to reach the limits required to quantify contaminants present at trace levels and benefit from its capacity for confirmation. Special attention is paid to the stationary and mobile phases commonly used in terms of the advantages that they offer compared to reversed-phase columns and the high-water content mobile phases traditionally used in RPLC. The most important features related to the matrices and contaminants normally studied are also discussed, as well as the contribution of the HILIC mode towards reducing the matrix effect.

Research group: Grup de Cromatografia. Aplicacions Mediambientals

Thematic Areas: Química Química Chemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 0165-9936

Author identifier: 0000-0003-2718-9336; ; ; 0000-0002-5667-2899

Record's date: 2018-02-28

Last page: 149

Journal volume: 94

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: https://www.sciencedirect.com/science/article/pii/S0165993617301231

Funding program: plan; Excelencia; CTQ2014-52617-P plan; PhD grant; BES-2012-057792

Article's DOI: 10.1016/j.trac.2017.07.017

Entity: Universitat Rovira i Virgili

Journal publication year: 2017

First page: 141

Publication Type: Article Artículo Article