Author, as appears in the article.: Rodríguez, A. ; Castro, E. ; Azmani, K. ; Hernandez, A. ; Aghabali, A. ; Liu, S. ; Metta-Magana, A. ; Olmstead, M. ; Poblet, J. M.; Echegoyen, L.

Department: Química Física i Inorgànica

URV's Author/s: RODRÍGUEZ FORTEA, ANTONIO; Castro, E. ; Azmani, K. ; Hernandez, A. ; Aghabali, A. ; Liu, S. ; Metta-Magana, A. ; Olmstead, M. ; POBLET RIUS, JOSEP MARIA; Echegoyen, L.

Keywords: fullerenes hexa-adducts trans-1

Abstract: A totally unanticipated regio- and stereo-isomerically pure C2h-symmetric trans-1-(bis-pyrrolidine)-tetra-malonate hexa-adduct of C60 was obtained via a topologically controlled method, followed by a 1,3-dipolar cycloaddition reaction. The structures of the products were elucidated by 1H- and 13C-NMR and by X-ray crystallography. The unexpected regio- and stereo-selectivity supported by theoretical calculations, was found to be mediated by the malonate-pyrrolidine interaction.

Research group: Química Quàntica

Thematic Areas: Química Química Chemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 0947-6539

Author identifier: 0000-0001-5884-5629; ; ; ; ; ; ; ; 0000-0002-4533-0623;

Record's date: 2018-03-01

Last page: 15944

Journal volume: 63

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2017/DT/C7DT03520A#!divAbstract

Funding program: plan; Excelencia; CTQ2014-52774-P altres; Grupos Consolidados; 2014SGR199 altres; ICREA Academia; ICREA Academia

Article's DOI: 10.1039/c7dt03520a

Entity: Universitat Rovira i Virgili

Journal publication year: 2017

First page: 15937

Publication Type: Article Artículo Article