Articles producció científica> Química Física i Inorgànica

Transition-metal-free B-B and B-interelement reactions with organic molecules 

  • Identification data

    Identifier: PC:3198
    Handle: http://hdl.handle.net/20.500.11797/PC3198
  • Authors:

    Fernández, E.
    Cuenca, A. B.
    Shishido, R.
    Ito, H.
  • Others:

    Author, as appears in the article.: Fernández, E. ; Cuenca, A. B. ; Shishido, R. ; Ito, H.
    Department: Química Física i Inorgànica
    URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Cuenca, A. B. ; Shishido, R. ; Ito, H.
    Keywords: Transition-metal-free B-B activation modes
    Abstract: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of the B-B and B-interelement bonds, as well as the generation of the new C-B and C-interelement bonds, in a selective way. The greener consequences of those novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidences that support the innovative theories, are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Chemistry Química Química
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0306-0012
    Author identifier: 0000-0001-9025-1791; ; ;
    Record's date: 2018-03-08
    Last page: 30
    Journal volume: 46
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2017/CS/C6CS00692B#!divAbstract
    Article's DOI: 10.1039/c6cs00692b
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    First page: 415
    Publication Type: Article Artículo Article
  • Keywords:

    Metalls de transició
    Catàlisi homogènia
    Compostos organometàl·lics
    Transition-metal-free B-B
    activation modes
    Chemistry
    Química
    Química
    0306-0012
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