Author, as appears in the article.: Fernández, E. ; Miralles, N. ; Gómez, J. E. ; Kleij, A.

Department: Química Física i Inorgànica

URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Miralles, N. ; Gómez, J. E. ; Kleij, A.

Keywords: Copper-Mediated SN2 Allyl Boryl Coupling Allyl Alkyl coupling

Abstract: A method for the copper-catalyzed borylmethylation and borylation of vinyl cyclic carbonates through an SN2¿ mechanism is reported. These singular reactions involve selective SN2¿ allylic substitutions with concomitant ring opening of the cyclic carbonate, and with extrusion of CO2 and formation of a useful hydroxyl functionality in a single step. The stereoselectivity of the homoallylic borylation and allylic borylation processes can be controlled, and synthetically useful unsaturated (E)-pent-2-ene-1,5-diols and (E)-but-2-ene-1,4-diols accessed

Research group: Organometàl.lics i Catàlisi Homogènia

Thematic Areas: Química Química Chemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 1523-7060

Author identifier: 0000-0001-9025-1791; ; ;

Record's date: 2018-03-08

Last page: 6099

Journal volume: 19

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: https://pubs-acs-org.sabidi.urv.cat/doi/abs/10.1021/acs.orglett.7b02947

Funding program: plan; Excelencia; CTQ2016-80328-P plan; CTQ-2014¿60419-R altres; Severo Ochoa Excellence Accreditation 2014¿2018 ; SEV-2013¿0319

Article's DOI: 10.1021/acs.orglett.7b02947

Entity: Universitat Rovira i Virgili

Journal publication year: 2017

First page: 6096

Publication Type: Article Artículo Article