Author, as appears in the article.: Fernández, E. ; Miralles, N. ; Alam, R. ; Szabó, K.

Department: Química Física i Inorgànica

URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Miralles, N. ; Alam, R. ; Szabó, K.

Keywords: allyl boronates allylic alcohols allylic borylation

Abstract: The base-catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1-disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid-base adduct, [Hbase]+[MeO-B2pin2]- favoured the formation of 1,2,3-triborylated species from the tertiary allylic alcohols and 1-propargylic cyclohexanol, at 90ºC.

Research group: Organometàl.lics i Catàlisi Homogènia

Thematic Areas: Química Química Chemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 1433-7851

Author identifier: 0000-0001-9025-1791; 0000-0001-8598-0252; ;

Record's date: 2018-03-08

Last page: 4307

Journal volume: 55

Papper version: info:eu-repo/semantics/publishedVersion

Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/anie.201511255/abstract;jsessionid=3F8421836029BE6CE1432568D9FD2BEA.f01t04

Funding program: plan; Excelencia; CTQ2013-43395P

Article's DOI: 10.1002/anie.201511255

Entity: Universitat Rovira i Virgili

Journal publication year: 2016

First page: 4303

Publication Type: Article Artículo Article