Author, as appears in the article.: Fernández, E. ; León, L.

Department: Química Física i Inorgànica

URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; León, L.

Keywords: Pauson¿Khand reaction alkynylboronic esters

Abstract: The first intermolecular Pauson-Khand reaction conduct-ed with internal alkynylboronic esters has been described. This strategy allows the installation of the boronic ester moiety in ¿-position of the cyclopentenone with total re-gio- and stereoselectivity. More interestingly, the resulting adduct can be subsequently derivatized by Suzuki-Miyaura cross-coupling reaction allowing any combination of ¿,¿-disubstituted cyclopentenones, solving, thus, a well-known and long-standing drawback about regioselectivity in Pauson-Khand reaction

Research group: Organometàl.lics i Catàlisi Homogènia

Thematic Areas: Química Química Chemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 1359-7345

Author identifier: 0000-0001-9025-1791;

Record's date: 2018-03-08

Papper version: info:eu-repo/semantics/publishedVersion

Link to the original source: http://pubs.rsc.org/en/content/articlepdf/2016/cc/c6cc04717c

Funding program: plan; Excelencia; CTQ2013-43395-P altres; Acció; TECSPR13-1-0040

Article's DOI: 10.1039/c6cc04717c

Entity: Universitat Rovira i Virgili

Journal publication year: 2016

Publication Type: Article Artículo Article