Articles producció científica> Química Física i Inorgànica

Transition-metal-free B-B and B-interelement reactions with organic molecules

  • Identification data

    Identifier: imarina:2794970
    Handle: http://hdl.handle.net/20.500.11797/imarina2794970
  • Authors:

    Cuenca, Ana B.
    Shishido, Ryosuke
    Ito, Hajime
    Fernandez, Elena
  • Others:

    Author, as appears in the article.: Cuenca, Ana B.; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena;
    Department: Química Física i Inorgànica
    URV's Author/s: Fernández Gutiérrez, Maria Elena
    Keywords: Unsaturated-compounds Transition-metal-free b-b Terminal alkynes N-heterocyclic carbenes Iminium ion generators Free borylation Diboron tetrachloride Catalyzed diboration Boron conjugate addition Bond formation Acyclic alpha,beta-unsaturated carbonyls Activation modes
    Abstract: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of B-B and B-interelement bonds, as well as the generation of new C-B and C-interelement bonds, in a selective way. The greener consequences of these novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidence that supports the innovative theories are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field.
    Thematic Areas: Química Materiais General medicine General chemistry Ciências biológicas ii Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Antropologia / arqueologia
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 14604744
    Author's mail: mariaelena.fernandez@urv.cat
    Author identifier: 0000-0001-9025-1791
    Record's date: 2023-02-18
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2017/cs/c6cs00692b#!divAbstract
    Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Chemical Society Reviews. 46 (2): 415-430
    APA: Cuenca, Ana B.; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena; (2017). Transition-metal-free B-B and B-interelement reactions with organic molecules. Chemical Society Reviews, 46(2), 415-430. DOI: 10.1039/c6cs00692b
    Article's DOI: 10.1039/c6cs00692b
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    Publication Type: Journal Publications
  • Keywords:

    Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Unsaturated-compounds
    Transition-metal-free b-b
    Terminal alkynes
    N-heterocyclic carbenes
    Iminium ion generators
    Free borylation
    Diboron tetrachloride
    Catalyzed diboration
    Boron conjugate addition
    Bond formation
    Acyclic alpha,beta-unsaturated carbonyls
    Activation modes
    Química
    Materiais
    General medicine
    General chemistry
    Ciências biológicas ii
    Ciência de alimentos
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Antropologia / arqueologia
  • Documents:

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