Author, as appears in the article.: Biosca M; Magre M; Pàmies O; Diéguez M

Department: Química Física i Inorgànica

URV's Author/s: Biosca Brull, Maria / Diéguez Fernández, Montserrat / Pamies Ollé, Oscar

Keywords: Unfunctionalized olefins P,n-ligands Iridium Cyclic β-enamides Cyclic ?-enamides Asymmetric hydrogenation

Abstract: © 2018 American Chemical Society. We have developed a family of Ir-P,oxazoline catalysts for asymmetric hydrogenation. These catalysts, with a simple modular architecture, have shown a high tolerance to the olefin geometry and substitution pattern, and to the presence of several neighboring polar groups. Thus, they were able to successfully hydrogenate disubstituted, trisubstituted, and tetrasubstituted minimally functionalized olefins (with enantiomeric excess values up to 99%). The excellent catalytic performance was also extended to the hydrogenation of cyclic β-enamides.

Thematic Areas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 21555435

Author's mail: maria.biosca@urv.cat montserrat.dieguez@urv.cat oscar.pamies@urv.cat

Author identifier: 0000-0002-9116-6318 0000-0002-8450-0656 0000-0002-2352-8508

Last page: 10320

Record's date: 2023-02-22

Journal volume: 8

Papper version: info:eu-repo/semantics/submittedVersion

Link to the original source: https://pubs.acs.org/doi/10.1021/acscatal.8b03170

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Acs Catalysis. 8 (11): 10316-10320

APA: Biosca M; Magre M; Pàmies O; Diéguez M (2018). Asymmetric Hydrogenation of Disubstituted, Trisubstituted, and Tetrasubstituted Minimally Functionalized Olefins and Cyclic β-Enamides with Easily Accessible Ir-P,Oxazoline Catalysts. Acs Catalysis, 8(11), 10316-10320. DOI: 10.1021/acscatal.8b03170

Article's DOI: 10.1021/acscatal.8b03170

Entity: Universitat Rovira i Virgili

Journal publication year: 2018

First page: 10316

Publication Type: Journal Publications