Author, as appears in the article.: Biosca M, Salomó E, de la Cruz-Sánchez P, Riera A, Verdaguer X, Pàmies O, Diéguez M

Department: Química Física i Inorgànica

URV's Author/s: Biosca Brull, Maria / Diéguez Fernández, Montserrat / Pamies Ollé, Oscar

Keywords: Phosphorus ligands Asymmetric hydrogenation

Abstract: Air-stable and readily available Ir-catalyst precursors modified with MaxPHOX-type ligands have been successfully applied in the challenging asymmetric hydrogenation of tetrasubstituted olefins under mild reaction conditions. Gratifyingly, these catalyst precursors are able to efficiently hydrogenate not only a range of indene derivatives (ee's up to 96%) but also 1,2-dihydronapthalene derivatives and acyclic olefins (ee's up to 99%), which both constitute the most challenging substrates for this transformation.

Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina ii Medicina i Materiais Interdisciplinar General medicine Farmacia Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, organic Biotecnología Biodiversidade Biochemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 15237060

Author's mail: maria.biosca@urv.cat montserrat.dieguez@urv.cat oscar.pamies@urv.cat

Author identifier: 0000-0002-9116-6318 0000-0002-8450-0656 0000-0002-2352-8508

Last page: 811

Record's date: 2023-02-22

Journal volume: 21

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.8b04084

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Organic Letters. 21 (3): 807-811

APA: Biosca M, Salomó E, de la Cruz-Sánchez P, Riera A, Verdaguer X, Pàmies O, Diéguez M (2019). Extending the Substrate Scope in the Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with Ir-P Stereogenic Aminophosphine-Oxazoline Catalysts. Organic Letters, 21(3), 807-811. DOI: 10.1021/acs.orglett.8b04084

Article's DOI: 10.1021/acs.orglett.8b04084

Entity: Universitat Rovira i Virgili

Journal publication year: 2019

First page: 807

Publication Type: Journal Publications