Author, as appears in the article.: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J.; Vicario, Jose L.; Fernandez, Elena;

Department: Química Física i Inorgànica

URV's Author/s: Fernández Gutiérrez, Maria Elena / MIRALLES PRAT, NURIA

Keywords: Transition-metal free Stereoselectivity Density functional calculations Borylation Allenamines stereoselectivity density functional calculations borylation allenamines

Abstract: Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.

Thematic Areas: Química Organic chemistry Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biotecnología Biodiversidade Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 15213765

Author's mail: mariaelena.fernandez@urv.cat

Author identifier: 0000-0001-9025-1791

Record's date: 2023-07-31

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803004

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Chemistry-A European Journal. 24 (53): 14059-14063

APA: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J.; Vicario, Jose L.; Fernandez, Elena; (2018). Transition-metal-free stereoselective borylation of allenamides. Chemistry-A European Journal, 24(53), 14059-14063. DOI: 10.1002/chem.201803004

Article's DOI: 10.1002/chem.201803004

Entity: Universitat Rovira i Virgili

Journal publication year: 2018

Publication Type: Journal Publications