Articles producció científica> Química Analítica i Química Orgànica

Me6-TREN/TREN Mixed-Ligand Effect During SET-LRP in the Catalytically Active DMSO Revitalizes TREN into an Excellent Ligand

  • Identification data

    Identifier: imarina:6389848
  • Authors:

    Maurya DS
    Malik A
    Feng X
    Bensabeh N
    Lligadas G
    Percec V
  • Others:

    Author, as appears in the article.: Maurya DS; Malik A; Feng X; Bensabeh N; Lligadas G; Percec V
    Department: Química Analítica i Química Orgànica
    URV's Author/s: Lligadas Puig, Gerard
    Keywords: Single-electron-transfer Pd catalyst Methyl acrylate Living radical polymerization Heteroaryl mesylates Cu(0) Complete conversion Chain-end functionality Biphasic mixtures Aryl mesylates
    Abstract: A mixed-ligand effect was observed for mixtures of tris(2-dimethylaminoethyl)amine (Me6-TREN) with tris(2-aminoethyl)amine (TREN) ligands during Cu(0) wire-catalyzed, single-electron transfer-living radical polymerization (SET-LRP) of methyl acrylate (MA) initiated with bis(2-bromopropionyl)ethane (BPE) in DMSO. The external order of reaction of SET-LRP both in the presence of Me6-TREN, TREN and of the mixed-ligand Me6-TREN/TREN, in DMSO, demonstrated a catalytic activity for DMSO similar to that reported in the presence of Cu(0) powder. The catalytic activity of DMSO, with close to 100% chain-end functionality, facilitates the much less expensive TREN to act as a very efficient ligand that is competitive with Me6-TREN and with the mixed-ligand and revitalizes TREN into an excellent ligand. The highest activity of the mixed-ligand at 1/1 ratio between ligands suggests that in addition to a fast exchange between these two ligands, a new single dynamic ligand stabilized by hydrogen-bonding, may generate these results.
    Thematic Areas: Química Polymers and plastics Polymer science Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, organic Biotecnología Biomaterials Bioengineering Biochemistry & molecular biology Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1525-7797
    Author's mail: gerard.lligadas@urv.cat
    Author identifier: 0000-0002-8519-1840
    Last page: 1919
    Record's date: 2023-02-26
    Journal volume: 21
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://pubs.acs.org/doi/10.1021/acs.biomac.9b01765
    Papper original source: Biomacromolecules. 21 (5): 1902-1919
    APA: Maurya DS; Malik A; Feng X; Bensabeh N; Lligadas G; Percec V (2020). Me6-TREN/TREN Mixed-Ligand Effect During SET-LRP in the Catalytically Active DMSO Revitalizes TREN into an Excellent Ligand. Biomacromolecules, 21(5), 1902-1919. DOI: 10.1021/acs.biomac.9b01765
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1021/acs.biomac.9b01765
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2020
    First page: 1902
    Publication Type: Journal Publications
  • Keywords:

    Biochemistry & Molecular Biology,Bioengineering,Biomaterials,Chemistry, Organic,Materials Chemistry,Polymer Science,Polymers and Plastics
    Single-electron-transfer
    Pd catalyst
    Methyl acrylate
    Living radical polymerization
    Heteroaryl mesylates
    Cu(0)
    Complete conversion
    Chain-end functionality
    Biphasic mixtures
    Aryl mesylates
    Química
    Polymers and plastics
    Polymer science
    Medicina ii
    Materials chemistry
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, organic
    Biotecnología
    Biomaterials
    Bioengineering
    Biochemistry & molecular biology
    Astronomia / física
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