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Amidinium-Containing 2D [MnCr] Dimetallic Oxalate-Based Networks - The Influence on Structure and Magnetism Explored by Combining Experience and Theory

  • Identification data

    Identifier: PC:3126
    Authors:
    De Graaf, C.Maxim, C.Saureu, S.Ferlay, S.Wais, M.Robert, V.Train, C.
    Abstract:
    Three X2+ bisamidinium dications are used as template for the formation of oxalate-based bimetallic [MnCr] compounds 1-3 of formula X[MnII(CH3OH)CrIII(ox)3]2·nS (X2+ = C14N4H20 2+ (cation A, compound 1), C14O2N4H202+ (cation B, compound 2), C16N4H24 2+ (cation C, compound 3); n=4 (1-2), 2 (3); S= CH3OH (1-2), CH3CN (3)). The single-crystal X-rays analysis reveals that in 1-3, a Mn-Cr oxalate-bridged bimetallic coordination network is formed, displaying corrugated two-dimensional (2D) layers based on heptacoordinated manganese(II) ions, with six oxygen atoms from three bis(bidentate) oxalate ions and one oxygen atom from a coordinated methanol molecule in the coordination sphere. In all cases, the coordination environment of manganese(II) is close to a Capped Trigonal PRism (CTPR). This evolution is related to the disymmetrization of one of the three oxalate linkages. Measurements of the magnetic properties revealed a continuous increase of the χ MT product, where χ M is the magnetic susceptibility, when the temperature is lowered from 300K to 5K, indicating the presence of a dominant ferromagnetic interaction in 1-3. The Curie-Weiss temperatures deduced from the fit of the magnetic susceptibility in the paramagnetic phase are 5.87K, 4.40K and 3.98K for 1, 2 and 3 respectively. From a mean field approach, an average weak ferromagnetic exchange interaction of 0.62K, 0.42K and 0.54K respectively can be deduced. Ab initio calculations up to the DDCI-2 level were performed on [MnCr] dimeric units. They allow to evaluate the exchange interaction for each type of bridges present in the three compounds. An effect of the asymmetry of the bridge on the exchange interaction is observed but not in a systematic way.
  • Others:

    Author, as appears in the article.: De Graaf, C. ; Maxim, C. ; Saureu, S. ; Ferlay, S. ; Wais, M. ; Robert, V.; Train, C.
    Department: Química Física i Inorgànica
    URV's Author/s: DE GRAAF , CORNELIS; Maxim, C. ; Saureu, S. ; Ferlay, S. ; Wais, M. ; Robert, V.; Train, C.
    Keywords: Manganese Magnetic properties Ab initio calculations
    Abstract: Three X2+ bisamidinium dications are used as template for the formation of oxalate-based bimetallic [MnCr] compounds 1-3 of formula X[MnII(CH3OH)CrIII(ox)3]2·nS (X2+ = C14N4H20 2+ (cation A, compound 1), C14O2N4H202+ (cation B, compound 2), C16N4H24 2+ (cation C, compound 3); n=4 (1-2), 2 (3); S= CH3OH (1-2), CH3CN (3)). The single-crystal X-rays analysis reveals that in 1-3, a Mn-Cr oxalate-bridged bimetallic coordination network is formed, displaying corrugated two-dimensional (2D) layers based on heptacoordinated manganese(II) ions, with six oxygen atoms from three bis(bidentate) oxalate ions and one oxygen atom from a coordinated methanol molecule in the coordination sphere. In all cases, the coordination environment of manganese(II) is close to a Capped Trigonal PRism (CTPR). This evolution is related to the disymmetrization of one of the three oxalate linkages. Measurements of the magnetic properties revealed a continuous increase of the χ MT product, where χ M is the magnetic susceptibility, when the temperature is lowered from 300K to 5K, indicating the presence of a dominant ferromagnetic interaction in 1-3. The Curie-Weiss temperatures deduced from the fit of the magnetic susceptibility in the paramagnetic phase are 5.87K, 4.40K and 3.98K for 1, 2 and 3 respectively. From a mean field approach, an average weak ferromagnetic exchange interaction of 0.62K, 0.42K and 0.54K respectively can be deduced. Ab initio calculations up to the DDCI-2 level were performed on [MnCr] dimeric units. They allow to evaluate the exchange interaction for each type of bridges present in the three compounds. An effect of the asymmetry of the bridge on the exchange interaction is observed but not in a systematic way.
    Research group: Química Quàntica
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1434-1948
    Author identifier: 0000-0001-8114-6658; ; ; ; ; ;
    Record's date: 2018-02-28
    Papper version: info:eu-repo/semantics/submittedVersion
    Link to the original source: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201600514
    Funding program: plan; Excelencia; CTQ2014-58664-R
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1002/ejic.201600514
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    Publication Type: Article Artículo Article
  • Keywords:

    Manganès--Compostos--Propietats magnètiques
    Química quàntica
    Manganese
    Magnetic properties
    Ab initio calculations
    Química
    Química
    Chemistry
    1434-1948
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