Repositori institucional URV
Belongs to TFG:SerieGeneralQ collection
TITLE:
Un nou catalitzador de Zn per transformar CO2 en carbonats - TFG:299
Handle:
https://hdl.handle.net/20.500.11797/TFG299
Student:
López Redondo, Claudia Sara
Language:
cat
Title in original language:
Un nou catalitzador de Zn per transformar CO2 en carbonats
Title in different languages:
A new Zn catalyst to transform CO2 into carbonates
Keywords:
CO2, carbonates, catalyst
Subject:
Química
Abstract:
Abstract We report the efficient utilization of a transition metal complex based on an inexpensive and easy-to-handle 2,9-bis(imino)-1,10-phenanthronyl ligands as catalyst for the coupling of epoxides with carbon dioxide. This complex in the presence of tetrabutylamonium bromide produced a 77 % of carbonate conversion in the cycloaddition of CO2 and 1,2-epoxihexane at 30 bars, 80˚C in 20 h (0.1 mol % catalyst loading). The complex is stable under catalytic conditions and could be recycled by simple filtration maintaining the conversion in a second run.
Project director:
Masdéu Bultó, Anna Maria
Department:
Química Física i Inorgànica
Education area(s):
Química
Entity:
Universitat Rovira i Virgili (URV)
Creation date in repository:
2015-10-15
Work's public defense date:
2015-06-15
Academic year:
2014-2015
Confidenciality:
No
Subject areas:
Chemistry
Access rights:
info:eu-repo/semantics/openAccess
Type:
info:eu-repo/semantics/bachelorThesis
Contributor:
Masdéu Bultó, Anna Maria
Títol:
Un nou catalitzador de Zn per transformar CO2 en carbonats
Language:
cat
Subject:
Química
Chemistry
Química
Química
Creator:
López Redondo, Claudia Sara
Rights:
info:eu-repo/semantics/openAccess
Date:
2015-06-15
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