Uncovering the Mechanistic Insights of Cp*CoIII-catalyzed C–H Methylation Reactions

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Uncovering the Mechanistic Insights of Cp*CoIII-catalyzed C–H Methylation Reactions - TFG:6625

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https://hdl.handle.net/20.500.11797/TFG6625

Student:	Romero Ribas, Marta
Language:	en
Title in original language:	Uncovering the Mechanistic Insights of Cp*CoIII-catalyzed C–H Methylation Reactions
Keywords:	C-H methylation , mechanistic studies , Cp*Co(III)
Subject:	Metilació
Abstract:	This BSc thesis investigates the limited nucleophilic C-H couplings in directed C-H functionalization reactions using CpCoIII catalysts. Analogues of metalacyclic CpCoIII complexes were studied to understand the transmetalation and reductive elimination steps involved in Cp*Co-catalyzed C-H methylation reactions. The impact of coupling partners, additives and directing groups were evaluated by conducting reactions under different conditions. Preliminary results suggest a more complex mechanistic scenario and reveal that the directing group influences the reaction rate.
Project director:	Pérez Temprano, Mónica H.
Department:	Química Analítica i Química Orgànica
Education area(s):	Química
Entity:	Universitat Rovira i Virgili (URV)
Creation date in repository:	2024-01-16
Work's public defense date:	2023-06-28
Academic year:	2022-2023
Confidenciality:	No
Subject areas:	Chemistry
Access rights:	info:eu-repo/semantics/openAccess

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File	Description	Format
Memòria	Memory	application/pdf

Coverage:	No
Type:	info:eu-repo/semantics/bachelorThesis
Contributor:	Pérez Temprano, Mónica H.
Títol:	Uncovering the Mechanistic Insights of Cp*CoIII-catalyzed C–H Methylation Reactions
Language:	en
Subject:	Química Chemistry Química Metilació
Format:	Universitat Rovira i Virgili (URV)
Creator:	Romero Ribas, Marta
Rights:	info:eu-repo/semantics/openAccess
Date:	2023-06-28

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