Repositori institucional URV
| URV's Author/s: | Fernández Gutiérrez, Maria Elena / Fernández López, Elena / ROYES BUISAN, JORDI |
| Author, as appears in the article.: | Royes, Jordi; Cuenca, Ana B; Fernandez, Elena |
| Author's mail: | mariaelena.fernandez@urv.cat |
| Author identifier: | 0000-0001-9025-1791 |
| Journal publication year: | 2018 |
| Publication Type: | Journal Publications |
| ISSN: | 1434193X |
| APA: | Royes, Jordi; Cuenca, Ana B; Fernandez, Elena (2018). Access to 1,1-Diborylalkenes and Concomitant Stereoselective Reactivity. European Journal Of Organic Chemistry, 2018(22), 2728-2739. DOI: 10.1002/ejoc.201701786 |
| Paper original source: | European Journal Of Organic Chemistry. 2018 (22): 2728-2739 |
| Abstract: | Gem-diborylalkenes have emerged as efficient reagents for selective cross-coupling reactions, reduction approaches and Michael additions. The synthesis of the 1,1-diborylalkenes involves condensation of polyborated compounds with aldehydes or ketones followed by B-O elimination, geminal diboration of 1,1-dihaloalkenes, 1-haloalkenes as well as terminal alkynes, dehydrogenative borylation of alkenes, borylation of alkynylboronates and hydroboration of alkynylboronates. These new set of reactions become general for a wide range of substrates and they can be understood by complementary mechanisms. |
| Article's DOI: | 10.1002/ejoc.201701786 |
| Link to the original source: | https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.201701786 |
| Paper version: | info:eu-repo/semantics/acceptedVersion |
| licence for use: | https://creativecommons.org/licenses/by/3.0/es/ |
| Department: | Química Física i Inorgànica |
| Licence document URL: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
| Thematic Areas: | Química Physical and theoretical chemistry Organic chemistry Materiais Interdisciplinar Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências agrárias i Ciência de alimentos Chemistry, organic Biotecnología Biodiversidade Astronomia / física |
| Keywords: | Stereoselectivity Reaction mechanisms Diboration Cross-coupling Borylation Boranes |
| Entity: | Universitat Rovira i Virgili |
| Record's date: | 2025-02-18 |
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