Repositori institucional URV
| URV's Author/s: | Casanova Chafer, Juan / Llobet Valero, Eduard |
| Author, as appears in the article.: | Moncea, Oana Casanova-Chafer, Juan Poinsot, Didier Ochmann, Lukas Mboyi, Cleve D. Nasrallah, Houssein O. Llobet, Eduard Makni, Imen El Atrous, Molka Brandes, Stephane Rousselin, Yoann Domenichini, Bruno Nuns, Nicolas Fokin, Andrey A. Schreiner, Peter R. Hierso, Jean-Cyrille |
| Author's mail: | juan.casanova@urv.cat eduard.llobet@urv.cat |
| Author identifier: | 0000-0001-6164-4342 |
| Journal publication year: | 2019 |
| Publication Type: | Journal Publications |
| ISSN: | 14337851 |
| APA: | Moncea, Oana Casanova-Chafer, Juan Poinsot, Didier Ochmann, Lukas Mboyi, Cleve D. Nasrallah, Houssein O. Llobet, Eduard Makni, Imen El Atrous, Molka B (2019). Diamondoid Nanostructures as sp3-Carbon-Based Gas Sensors. Angewandte Chemie (International Ed. Print), 58(29), 9933-9938. DOI: 10.1002/anie.201903089 |
| Papper original source: | Angewandte Chemie (International Ed. Print). 58 (29): 9933-9938 |
| Abstract: | Diamondoids, sp3 -hybridized nanometer-sized diamond-like hydrocarbons (nanodiamonds), difunctionalized with hydroxy and primary phosphine oxide groups, enable the assembly of the first sp3 -C-based chemical sensors by vapor deposition. Both pristine nanodiamonds and palladium nanolayered composites can be used to detect toxic NO2 and NH3 gases. This carbon-based gas sensor technology allows reversible NO2 detection down to 50?ppb and NH3 detection at 25-100?ppm concentration with fast response and recovery processes at 100?°C. Reversible gas adsorption and detection is compatible with 50?% humidity conditions. Semiconducting p-type sensing properties are achieved from devices based on primary phosphine-diamantanol, in which high specific area (ca. 140?m2 ?g-1 ) and channel nanoporosity derive from H-bonding.© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Article's DOI: | 10.1002/anie.201903089 |
| Link to the original source: | https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201903089 |
| Papper version: | info:eu-repo/semantics/acceptedVersion |
| licence for use: | https://creativecommons.org/licenses/by/3.0/es/ |
| Department: | Enginyeria Electrònica, Elèctrica i Automàtica |
| Licence document URL: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
| Thematic Areas: | Química Medicina ii Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Astronomia / física |
| Keywords: | Phosphine Palladium Nanodiamonds Hybrid materials Gas sensing palladium nanodiamonds hybrid materials gas sensing |
| Entity: | Universitat Rovira i Virgili |
| Record's date: | 2024-07-27 |
| Search your record at: |   |
| File | Description | Format | |
|---|---|---|---|
| DocumentPrincipal | DocumentPrincipal | application/pdf |
© 2011 Universitat Rovira i Virgili