Repositori institucional URV
| URV's Author/s: | Boutureira Martín, Omar / Castillón Miranda, Sergio / Mestre Ventura, Jordi |
| Author, as appears in the article.: | Mestre, Jordi; Castillon, Sergio; Boutureira, Omar |
| Author's mail: | omar.boutureira@urv.cat sergio.castillon@urv.cat |
| Author identifier: | 0000-0002-0768-8309 0000-0002-0690-7549 |
| Journal publication year: | 2019 |
| Publication Type: | Journal Publications |
| ISSN: | 00223263 |
| APA: | Mestre, Jordi; Castillon, Sergio; Boutureira, Omar (2019). Ligandless Pentafluoroethylation of Unactivated (Hetero)aryl and Alkenyl Halides Enabled by the Controlled Self-Condensation of TMSCF3-Derived CuCF3. Journal Of Organic Chemistry, 84(23), 15087-15097. DOI: 10.1021/acs.joc.9b02001 |
| Paper original source: | Journal Of Organic Chemistry. 84 (23): 15087-15097 |
| Abstract: | Pentafluoroethylation of unactivated C(sp(2))-X bonds (X = I, Br) using a storable, ligandless CuC2F5 reagent prepared by controlled self-condensation of ready available TMSCF3-derived CuCF3 has been developed. A thorough analysis by F-19 NMR and ESI-MS revealed the nature of this reagent in solution. The operational simplicity and robustness of this system enables the efficient, late-stage incorporation of C2F5 units into a variety of (hetero)aryl and complex alkenyl halides such as glycals, nucleosides, and nucleobases. |
| Article's DOI: | 10.1021/acs.joc.9b02001 |
| Link to the original source: | https://pubs.acs.org/doi/10.1021/acs.joc.9b02001 |
| Paper version: | info:eu-repo/semantics/acceptedVersion |
| licence for use: | https://creativecommons.org/licenses/by/3.0/es/ |
| Department: | Química Analítica i Química Orgànica |
| Licence document URL: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
| Thematic Areas: | Química Organic chemistry Odontología Medicina ii Medicina i Materiais Interdisciplinar General medicine Farmacia Ensino Engenharias iv Engenharias ii Engenharias i Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, organic Biotecnología Astronomia / física |
| Keywords: | Trifluoromethylation Reagent Perfluoroalkylation Organic fluorine-compounds Fluoroalkylation reactions Copper Complexes Arylboronic acids Aryl iodides Aqueous-media |
| Entity: | Universitat Rovira i Virgili |
| Record's date: | 2024-11-30 |
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