Author, as appears in the article.: Mercè Coll; Oscar Pàmies; Montserrat Diéguez

Department: Química Física i Inorgànica

URV's Author/s: COLL SERRAHIMA, MARIA MERCÈ; PAMIES OLLÉ, OSCAR; DIÉGUEZ FERNÁNDEZ, MONTSERRAT

Keywords: palladium allylic substitution phosphite-thioether ligands

Abstract: A Pd-furanoside thioether-phosphite catalytic system that can create new C-C, C-N, and C-O bonds in several substrate types using a wide range of nucleophiles in high yields and enantioselectivities has been identified. Of particular note are the excellent enantioselectivities obtained in the etherification of linear and cyclic substrates. The potential application of the new Pd-thioether-phosphite catalytic systems was also demonstrated by the synthesis of the chiral carbo- and heterocycles.

Research group: Organometàl.lics i Catàlisi Homogènia

Thematic Areas: Química Química Chemistry

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 1523-7060

Author identifier: n/a; 0000-0002-2352-8508; 0000-0002-8450-0656

Record's date: 2017-02-22

Last page: 1895

Journal volume: 16

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: https://pubs.acs.org/doi/10.1021/ol500758y

Article's DOI: 10.1021/ol500758y

Entity: Universitat Rovira i Virgili

Journal publication year: 2014

First page: 1892

Publication Type: Post-print