Repositori institucional URV
| URV's Author/s: | ECHAVARREN PABLOS, ANTONIO MARIA; Mariia S. Kirillova; Michael E. Muratore; Ruth Dorel |
| Author, as appears in the article.: | Antonio M. Echavarren; Mariia S. Kirillova; Michael E. Muratore; Ruth Dorel |
| Author identifier: | 0000-0001-6808-3007; n/a; n/a; n/a |
| Journal publication year: | 2016 |
| Publication Type: | Article |
| ISSN: | 0002-7863 |
| Abstract: | The total synthesis of lundurines A-C has been accomplished in racemic and enantiopure forms in 11-13 and 12-14 steps, respectively, without protection/deprotection of functional groups, by a novel tandem double condensation/Claisen rearrangement, a gold(I)-catalyzed alkyne hydroarylation, a cyclopropanation via formal [3 + 2] cycloaddition/nitrogen extrusion, and a remarkable olefin migration through a vinylcyclopropane retro-ene/ene reaction that streamlines the endgame. |
| Article's DOI: | 10.1021/jacs.6b01428 |
| Link to the original source: | https://pubs.acs.org/doi/10.1021/jacs.6b01428 |
| Papper version: | info:eu-repo/semantics/publishedVersion |
| licence for use: | https://creativecommons.org/licenses/by/3.0/es/ |
| Department: | Química Analítica i Química Orgànica |
| Licence document URL: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
| Thematic Areas: | Chemistry |
| Keywords: | Synthesis (chemical) Gold catalysis |
| Entity: | Universitat Rovira i Virgili |
| Record's date: | 2016-05-02 |
| First page: | 3671 |
| Last page: | 3674 |
| Journal volume: | 138 |
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| File | Description | Format | |
|---|---|---|---|
| DocumentPrincipal | DocumentPrincipal | application/pdf |
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