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TITLE:
SYNTHESIS AND CHARACTERIZATION OF DIBENZOTHIOPHENE AND PHENOTHIAZINE DERIVATIVES FOR ORGANIC OPTOELECTRONIC DEVICES - TFG:119

Student:El Ouahabi, Fàtima
Language:en
Title in original language:SYNTHESIS AND CHARACTERIZATION OF DIBENZOTHIOPHENE AND PHENOTHIAZINE DERIVATIVES FOR ORGANIC OPTOELECTRONIC DEVICES
Title in different languages:SYNTHESIS AND CHARACTERIZATION OF DIBENZOTHIOPHENE AND PHENOTHIAZINE DERIVATIVES FOR ORGANIC OPTOELECTRONIC DEVICES
Keywords:Dibenzothiophene, phenothiazine, OLED
Subject:Compostos orgànics - Síntesi
Abstract:SUMMARY A family of benzothiophene and phenothiazine derivatives have been synthetized and characterized by Proton Nuclear Magnetic Resonance Spectroscopy and Mass Spectroscopy. Oxidation, Bromination, Alkylation and Iodination reactions have been carried out from 4,4-diphenylbromine, dibenzothiophene and phenothiazine using convergent synthesis according to yields and facilities of each reaction. The introduction of reactive functional groups as iodine and bromine in each case and alkyl chain for increase the solubility have been the main objectives of this project. 3,7-diiodobenzothiophene-S,S-dioxide,3,7-dibromobenzothiophene-S,S-dioxide and 3,7-dibromo-10-(2-ethylhexyl)-phenothiazine-5,5-dioxide are the target π-conjugated compounds which exhibit good charger transport properties according to viewed items. These aromatic compounds have been synthetized with good yields and used as starting compounds for the performance of Ullmann coupling and Buchwald–Hartwig amination reactions in order to try to obtain the last phenyl compounds which will be used for the manufacturing of optoelectronic devices.
Project director:Tomkevičienė, Aušra
Work's codirector:Seingeot, Adeline
Department:Química Analítica i Química Orgànica
Education area(s):Química
Entity:Universitat Rovira i Virgili (URV)
TFG credits:12
Creation date in repository:2015-02-18
Work's public defense date:2014-07-21
Academic year:2013-2014
Confidenciality:No
Subject areas:Chemistry
Access rights:info:eu-repo/semantics/openAccess
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