Repositori institucional URV
Belongs to TFG:SerieGeneralQUIMA collection
TITLE:
New stereoselective synthesis of trienes - TFG:6574
Handle:
https://hdl.handle.net/20.500.11797/TFG6574
Student:
Iragorri Molinero, Nerea
Language:
en
Title in original language:
New stereoselective synthesis of trienes
Subject:
Química orgànica
Abstract:
A new stereoselective synthesis of conjugated trienamides by means of an anionic cascade reaction has been reported when testing the influence of the sterics of the anion-accelerated amino-Cope reaction. By the direct g-selective union of a dienolate and a chiral conjugated sulfinyl imine containing bulky groups, a product containing a 3-double bonds conjugated system is obtained. This contrasts with the six-membered ring product obtained when the same reaction is performed with non-sterically hindered compounds. The same reaction was tested with chiral non-conjugated sulfinyl imines, and a 2-double bonds conjugated system product was obtained.
Project director:
Fernández Gutiérrez, Maria Elena
Work's codirector:
Njardarson, Jon
Department:
Química Analítica i Química Orgànica
Education area(s):
Química en anglès
Entity:
Universitat Rovira i Virgili (URV)
Creation date in repository:
2023-12-18
Work's public defense date:
2023-06-27
Academic year:
2022-2023
Confidenciality:
No
Subject areas:
Chemistry
Access rights:
info:eu-repo/semantics/openAccess
Coverage:
No
Type:
info:eu-repo/semantics/bachelorThesis
Contributor:
Njardarson, Jon
Fernández Gutiérrez, Maria Elena
Títol:
New stereoselective synthesis of trienes
Language:
en
Subject:
Química
Chemistry
Química
Química orgànica
Format:
Universitat Rovira i Virgili (URV)
Creator:
Iragorri Molinero, Nerea
Rights:
info:eu-repo/semantics/openAccess
Date:
2023-06-27
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