Repositori institucional URV
| URV's Author/s: | Roig Gibert, Adrià |
| Author, as appears in the article.: | Vilanova-Pérez, A; Moradi, S; Konuray, O; Ramis, X; Roig, A; Fernández-Francos, X |
| Author's mail: | adria.roig@urv.cat adria.roig@urv.cat |
| Journal publication year: | 2024 |
| Publication Type: | Journal Publications |
| APA: | Vilanova-Pérez, A; Moradi, S; Konuray, O; Ramis, X; Roig, A; Fernández-Francos, X (2024). Harnessing disulfide and transesterification bond exchange reactions for recyclable and reprocessable 3D-printed vitrimers. Reactive & Functional Polymers, 195(), 105825-. DOI: 10.1016/j.reactfunctpolym.2023.105825 |
| Papper original source: | Reactive & Functional Polymers. 195 105825- |
| Abstract: | Two new vitrimeric materials have been studied for potential additive manufacturing applications such as 3Dprinting. A monomer containing disulfide bonds and beta-hydroxyesters was easily synthesized from two lowcost and commercially available reagents. Another disulfide-containing monomer was synthesized for comparison purposes. Materials were prepared through a UV-light radical polymerization of methacrylates. The addition of two reactive diluents such as poly(ethylene glycol) methyl ether methacrylate (PEGMA) and ethylene glycol phenyl ether methacrylate (EGPMA) was necessary to achieve a suitable viscosity for the curing as well as for their printability. The curing process was controlled by FTIR. Thermomechanical properties were investigated by means of DMTA analysis revealing near-ambient T-g values. Stress relaxation tests revealed that both materials were capable to relax the 63% of the initial stress in less than 10 min at 110( degrees)C. The recyclability of the materials was achieved, and the mechanical and thermomechanical properties of the recycled samples were compared to the virgin ones revealing a great recovery of the initial properties. Finally, Digital Light Processing (DLP) technique was used to print complex structures with high resolution highlighting the great potential of these vitrimeric materials in 3D printing. |
| Article's DOI: | 10.1016/j.reactfunctpolym.2023.105825 |
| Link to the original source: | https://www.sciencedirect.com/science/article/pii/S1381514823003280 |
| Papper version: | info:eu-repo/semantics/publishedVersion |
| licence for use: | https://creativecommons.org/licenses/by/3.0/es/ |
| Department: | Química Analítica i Química Orgànica |
| Licence document URL: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
| Thematic Areas: | Saúde coletiva Química Polymers and plastics Polymer science Medicina veterinaria Materials chemistry Materiais Interdisciplinar General chemistry General chemical engineering Farmacia Environmental chemistry Engineering, chemical Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, applied Chemistry (miscellaneous) Chemistry (all) Chemical engineering (miscellaneous) Chemical engineering (all) Biotecnología Biodiversidade Biochemistry Astronomia / física |
| Keywords: | Vitrimer Transesterification Temperature Recyclability Polymers Disulfide metathesis 3d-printing 3d |
| Entity: | Universitat Rovira i Virgili |
| Record's date: | 2024-08-03 |
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