Farah, M; Giralt, J; Stüber, F; Font, J; Fabregat, A; Fortuny, A (2023). Hollow fiber liquid membrane: A promising approach for elimination of pharmaceutical compounds from wastewater. Journal Of Environmental Chemical Engineering, 11(6), 111544-. DOI: 10.1016/j.jece.2023.111544
Papper original source:
Journal Of Environmental Chemical Engineering. 11 (6): 111544-
Abstract:
Pharmaceutical compounds present in water pose significant challenges, particularly due to their low concentrations in water streams. Hollow fiber liquid membranes provide a flexible and easily manageable solution, enabling the concentration of specific contaminants. This concentration step significantly improves their effective removal from water systems. The study focused on using hollow fiber liquid membrane technology to effectively remove diclofenac (DCF) and ibuprofen (IBU), two pharmaceutical compounds. A concentration of 40% Cyanex 923 (Cy923) dissolved in kerosene was selected as the preferred extractant due to its stability and quick extraction properties. The stability of the system was tested with a pseudo-emulsion, enabling repeated use of the system. Additionally, an analytical model was developed to calculate the membrane's permeability. In order to enhance the degradation and mineralization of the pharmaceutical compounds and their byproducts, ozonation was integrated with the hollow fiber liquid membrane system in a single system. Measurement of total organic carbon (TOC) revealed a significant reduction of 72% for diclofenac and 57% for ibuprofen with an initial ozone concentration of 10 mg/L and operating under the optimal conditions of hollow fiber liquid membrane.
Pharmaceutical compounds present in water pose significant challenges, particularly due to their low concentrations in water streams. Hollow fiber liquid membranes provide a flexible and easily manageable solution, enabling the concentration of specific contaminants. This concentration step significantly improves their effective removal from water systems. The study focused on using hollow fiber liquid membrane technology to effectively remove diclofenac (DCF) and ibuprofen (IBU), two pharmaceutical compounds. A concentration of 40% Cyanex 923 (Cy923) dissolved in kerosene was selected as the preferred extractant due to its stability and quick extraction properties. The stability of the system was tested with a pseudo-emulsion, enabling repeated use of the system. Additionally, an analytical model was developed to calculate the membrane's permeability. In order to enhance the degradation and mineralization of the pharmaceutical compounds and their byproducts, ozonation was integrated with the hollow fiber liquid membrane system in a single system. Measurement of total organic carbon (TOC) revealed a significant reduction of 72% for diclofenac and 57% for ibuprofen with an initial ozone concentration of 10 mg/L and operating under the optimal conditions of hollow fiber liquid membrane.
Chemical Engineering (Miscellaneous),Engineering, Chemical,Engineering, Environmental,Pollution,Process Chemistry and Technology,Waste Management and Disposal Stability Removal Products Photocatalysis Pharmaceutical compounds Ozonation Neutral extractant Micropollutants Microextraction Liquid membrane Ibuprofen Diclofenac Degradation Chromatography Waste management and disposal Química Process chemistry and technology Pollution Materiais Matemática / probabilidade e estatística Interdisciplinar Farmacia Engineering, environmental Engineering, chemical Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemical engineering (miscellaneous) Biotecnología Astronomia / física