Repositori institucional URV
| URV's Author/s: | ECHAVARREN PABLOS, ANTONIO / Lerena Pérez, Laura |
| Author, as appears in the article.: | Lerena L; Zuzak R; Godlewski S; Echavarren AM |
| Author's mail: | laura.lerena@estudiants.urv.cat antoniomaria.echavarren@urv.cat |
| Author identifier: | 0000-0002-6418-7930 |
| Journal publication year: | 2024 |
| Publication Type: | Journal Publications |
| APA: | Lerena L; Zuzak R; Godlewski S; Echavarren AM (2024). The Journey for the Synthesis of Large Acenes. Chemistry-A European Journal, 30(57), -. DOI: 10.1002/chem.202402122 |
| Papper original source: | Chemistry-A European Journal. 30 (57): |
| Abstract: | Acenes, the group of polycyclic aromatic hydrocarbons (PAHs) with linearly fused benzene rings, possess distinctive electronic properties with potential applicability in material science. Hexacene was the largest acene obtained and characterized in the last century, followed by heptacene in 2006. Since then, a race for obtaining the largest acene resulted in the development of several members of this family as well as diverse innovative synthetic strategies, from solid-state chemistry to the promising on-surface chemistry. This last technique allows the obtention of large acenes, up to tridecacene, the largest acene so far. This review presents the different methodologies employed for the synthesis of acenes, highlighting the newest studies, to provide a much more thorough understanding of the essence of the electronic structure of this captivating group of organic compounds. Since the synthesis of heptacene in 2006, the race to obtain and study the properties of largest acenes resulted in the development of innovative synthetic strategies, from solid-state chemistry to on-surface chemistry. This review presents the different methodologies employed for the synthesis of large acenes, up to tridecacene, highlighting the newest studies. image |
| Article's DOI: | 10.1002/chem.202402122 |
| Link to the original source: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202402122 |
| Papper version: | info:eu-repo/semantics/publishedVersion |
| licence for use: | https://creativecommons.org/licenses/by/3.0/es/ |
| Department: | Química Analítica i Química Orgànica |
| Licence document URL: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
| Thematic Areas: | Astronomia / física Biodiversidade Biotecnología Catalysis Chemistry Chemistry (all) Chemistry (miscellaneous) Chemistry, multidisciplinary Ciências agrárias i Ciências biológicas i Ciências biológicas ii Ciências biológicas iii Engenharias ii Engenharias iii Farmacia General chemistry General medicine Interdisciplinar Materiais Medicina i Organic chemistry Química |
| Keywords: | Acenes Alpha-diketones Crystal-structure Electronic properties Field-effect transistors Heptacene Hexacene Homo-lumo gap On-surface On-surface synthesis Pentacene Photodetecto Polycyclic aromatic-hydrocarbons Semiconductors Solid-state Stability Synthesi Synthesis Tetracene |
| Entity: | Universitat Rovira i Virgili |
| Record's date: | 2024-10-26 |
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