Autor/es de la URV: | Alagh, Aanchal / Annanouch, Fatima Ezahra / Llobet Valero, Eduard |
Autor según el artículo: | Alagh, Aanchal; Annanouch, Fatima Ezahra; Umek, Polona; Bittencourt, Carla; Sierra-Castillo, Ayrton; Haye, Emile; Colomer, Jean Francois; Llobet, Eduard |
Direcció de correo del autor: | fatimaezahra.annanouch@urv.cat aanchal.alagh@estudiants.urv.cat aanchal.alagh@estudiants.urv.cat eduard.llobet@urv.cat |
Identificador del autor: | 0000-0003-1533-6482 0000-0003-2466-8219 0000-0003-2466-8219 0000-0001-6164-4342 |
Año de publicación de la revista: | 2021 |
Tipo de publicación: | Journal Publications |
ISSN: | 09254005 |
Referencia de l'ítem segons les normes APA: | Alagh, Aanchal; Annanouch, Fatima Ezahra; Umek, Polona; Bittencourt, Carla; Sierra-Castillo, Ayrton; Haye, Emile; Colomer, Jean Francois; Llobet, Edua (2021). CVD growth of self-assembled 2D and 1D WS2 nanomaterials for the ultrasensitive detection of NO2. Sensors And Actuators B-Chemical, 326(128813), 128813-. DOI: 10.1016/j.snb.2020.128813 |
Referencia al articulo segun fuente origial: | Sensors And Actuators B-Chemical. 326 (128813): 128813- |
Resumen: | © 2020 Elsevier B.V. Herein, we report for the first time on the facile synthesis of 2D layered WS2 nanosheets assembled on 1D WS2 nanostructures by combining the aerosol assisted chemical vapor deposition (AA-CVD) method with H2-free atmospheric pressure CVD, for an ultrasensitive detection of NO2. This synthesis strategy allows us a direct integration of the sensing material onto the sensor transducer with high growth yield and uniform coverage. Two different WS2 morphologies (nanotriangles and nanoflakes) were prepared and investigated. The results show that the assembly of layered WS2 nanosheets on a 3D architecture leads to an improvement in sensing performance by maintaining a high surface area in an accessible porous network. The sensors fabricated show stable, reproducible and remarkable responses towards NO2 at ppb concentration levels. The highest sensitivity was recorded for WS2 NT sensors, with an unprecedented ultra-low detection limit under 5 ppb. Additionally, this material has demonstrated its ability to detect 800 ppb of NO2 even when operated at room temperature (25 °C). Regarding humidity cross-sensitivity, our WS2 sensors remain stable and functional for detecting NO2 at ppb levels (i.e., a moderate response decrease is observed) when ambient humidity is raised to 50%. An 8-month long-term stability study has been conducted, which indicates that WS2-NT sensors show a very stable response to NO2 over time. |
DOI del artículo: | 10.1016/j.snb.2020.128813 |
Enlace a la fuente original: | https://www.sciencedirect.com/science/article/abs/pii/S0925400520311606 |
Versión del articulo depositado: | info:eu-repo/semantics/acceptedVersion |
Acceso a la licencia de uso: | https://creativecommons.org/licenses/by/3.0/es/ |
Departamento: | Enginyeria Electrònica, Elèctrica i Automàtica |
URL Documento de licencia: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
Áreas temáticas: | Surfaces, coatings and films Spectroscopy Química Odontología Nutrição Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar Instruments & instrumentation Instrumentation Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Electrochemistry Electrical and electronic engineering Educação física Educação Economia Condensed matter physics Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, analytical Biotecnología Biodiversidade Astronomia / física Analytical chemistry |
Palabras clave: | Ws2 Ws 2 Tmds Temperature Sensors Performance Monolayer ws2 Humidity Gas sensor Gas Fabrication Cvd Aerosol-assisted cvd Aacvd 2-dimensional sns2 |
Programa de financiación: | H2020- MSCA-RISE-2018 |
Acción del progama de financiación: | SMART SENSING FOR RAPID RESPONSE TO CHEMICAL THREATS ON SOFT TARGETS |
Acrónimo: | SENSOFT |
Código de proyecto: | Project Nr. 823895 |
Entidad: | Universitat Rovira i Virgili |
Fecha de alta del registro: | 2024-07-27 |
Descripción: | © 2020 Elsevier B.V. Herein, we report for the first time on the facile synthesis of 2D layered WS2 nanosheets assembled on 1D WS2 nanostructures by combining the aerosol assisted chemical vapor deposition (AA-CVD) method with H2-free atmospheric pressure CVD, for an ultrasensitive detection of NO2. This synthesis strategy allows us a direct integration of the sensing material onto the sensor transducer with high growth yield and uniform coverage. Two different WS2 morphologies (nanotriangles and nanoflakes) were prepared and investigated. The results show that the assembly of layered WS2 nanosheets on a 3D architecture leads to an improvement in sensing performance by maintaining a high surface area in an accessible porous network. The sensors fabricated show stable, reproducible and remarkable responses towards NO2 at ppb concentration levels. The highest sensitivity was recorded for WS2 NT sensors, with an unprecedented ultra-low detection limit under 5 ppb. Additionally, this material has demonstrated its ability to detect 800 ppb of NO2 even when operated at room temperature (25 °C). Regarding humidity cross-sensitivity, our WS2 sensors remain stable and functional for detecting NO2 at ppb levels (i.e., a moderate response decrease is observed) when ambient humidity is raised to 50%. An 8-month long-term stability study has been conducted, which indicates that WS2-NT sensors show a very stable response to NO2 over time. |
Tipo: | Journal Publications |
Coautor: | Universitat Rovira i Virgili |
Títol: | CVD growth of self-assembled 2D and 1D WS2 nanomaterials for the ultrasensitive detection of NO2 |
Materia: | Chemistry, Analytical,Condensed Matter Physics,Electrical and Electronic Engineering,Electrochemistry,Electronic, Optical and Magnetic Materials,Instrumentation,Instruments & Instrumentation,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films Ws2 Ws 2 Tmds Temperature Sensors Performance Monolayer ws2 Humidity Gas sensor Gas Fabrication Cvd Aerosol-assisted cvd Aacvd 2-dimensional sns2 Surfaces, coatings and films Spectroscopy Química Odontología Nutrição Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar Instruments & instrumentation Instrumentation Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Electrochemistry Electrical and electronic engineering Educação física Educação Economia Condensed matter physics Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, analytical Biotecnología Biodiversidade Astronomia / física Analytical chemistry |
Fecha: | 2021 |
Autor: | Alagh, Aanchal Annanouch, Fatima Ezahra Umek, Polona Bittencourt, Carla Sierra-Castillo, Ayrton Haye, Emile Colomer, Jean Francois Llobet, Eduard |
Derechos: | info:eu-repo/semantics/openAccess |
Busca tu registro en: |
Archivo | Descripción | Formato | |
---|---|---|---|
DocumentPrincipal | DocumentPrincipal | application/pdf |
© 2011 Universitat Rovira i Virgili