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Controlled composite processing based on off-stoichiometric thiol-epoxy dual-curing systems with sequential heat release (SHR) - imarina:9241739

Autor/s de la URV:Fabregat Sanjuan, Albert / Fernández Francos, Xavier
Autor segons l'article:Fabregat-Sanjuan, Albert; Fernandez-Francos, Xavier; Ferrando-Piera, Francesc;
Adreça de correu electrònic de l'autor:xavier.fernandez@urv.cat
a.fabregat@urv.cat
Identificador de l'autor:0000-0002-3492-2922
0000-0002-2878-1369
Any de publicació de la revista:2022
Tipus de publicació:Journal Publications
Referència de l'ítem segons les normes APA:Fabregat-Sanjuan, Albert; Fernandez-Francos, Xavier; Ferrando-Piera, Francesc; (2022). Controlled composite processing based on off-stoichiometric thiol-epoxy dual-curing systems with sequential heat release (SHR). Journal Of Applied Polymer Science, 139(17), -. DOI: 10.1002/app.52009
Referència a l'article segons font original:Journal Of Applied Polymer Science. 139 (17):
Resum:Control of curing rate and exothermicity during processing of thermosetting composite materials is essential in order to minimize the formation of internal stresses leading to mechanical and dimensional defects in the samples, especially in thick composite samples. It was recently proposed that sequential heat release, an approach based on the kinetic control of the curing sequence of dual-curing thermosets, would enable a step-wise release of the reaction heat and therefore a better control of conversion and temperature profiles during the crosslinking stage. In this article, it is shown experimental proof of this concept obtained by means of an instrumented mold that can be used for the processing of small samples with and without carbon fiber reinforcement. Safe processing scenarios have been defined by numerical simulation using a simplified two-dimensional heat transfer model and validated experimentally.
DOI de l'article:10.1002/app.52009
Enllaç font original:https://onlinelibrary.wiley.com/doi/full/10.1002/app.52009
Versió de l'article dipositat:info:eu-repo/semantics/publishedVersion
Accès a la llicència d'ús:https://creativecommons.org/licenses/by/3.0/es/
Departament:Enginyeria Mecànica
URL Document de llicència:https://repositori.urv.cat/ca/proteccio-de-dades/
Àrees temàtiques:Surfaces, coatings and films
Química
Polymers and plastics
Polymer science
Odontología
Nutrição
Medicina ii
Medicina i
Materials chemistry
Materiais
Interdisciplinar
Geociências
General chemistry
Farmacia
Ensino
Engenharias iv
Engenharias iii
Engenharias ii
Engenharias i
Ciências biológicas iii
Ciências biológicas ii
Ciências biológicas i
Ciências ambientais
Ciências agrárias i
Ciência de alimentos
Ciência da computação
Chemistry (miscellaneous)
Chemistry (all)
Biotecnología
Astronomia / física
Paraules clau:Thermosetting composites
Thermosets
Thermal properties
Temperature
Structure-property relationships
Structure-properties relationships
Stresses
Optimization
Kinetics
Heat transfer
Heat release
Exothermicity
Epoxy
Dual curing
Curing system
Curing rates
Curing
Cure
Crosslinking
Composites material
Composites
Composite processing
Carbon fibers
Entitat:Universitat Rovira i Virgili
Data d'alta del registre:2024-09-07
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