Repositori institucional URV
| Autor/s de la URV: | Marsal Garví, Luis Francisco / Pallarès Marzal, Josep / SANCHEZ LÓPEZ, JOSÉ GUADALUPE |
| Autor segons l'article: | Alvaro-Martins, Maria J; Sanchez, Jose G; Lavarda, Giulia; Molina, Desire; Pallares, Josep; Torres, Tomas; Marsal, Lluis F; Sastre-Santos, Angela |
| Adreça de correu electrònic de l'autor: | lluis.marsal@urv.cat josep.pallares@urv.cat |
| Identificador de l'autor: | 0000-0002-5976-1408 0000-0001-7221-5383 |
| Any de publicació de la revista: | 2021 |
| Tipus de publicació: | Journal Publications |
| Referència de l'ítem segons les normes APA: | Alvaro-Martins, Maria J; Sanchez, Jose G; Lavarda, Giulia; Molina, Desire; Pallares, Josep; Torres, Tomas; Marsal, Lluis F; Sastre-Santos, Angela (2021). Subphthalocyanine-Diketopyrrolopyrrole Conjugates: 3D Star-Shaped Systems as Non-Fullerene Acceptors in Polymer Solar Cells with High Open-Circuit Voltage. Chempluschem, 86(10), 1360-1361. DOI: 10.1002/cplu.202100103 |
| Referència a l'article segons font original: | Chempluschem. 86 (10): 1360-1361 |
| Resum: | Four star-shaped electron acceptors (C-1-OPh, C-3-OPh, C-1-Cl and C-3-Cl) based on a subphthalocyanine core bearing three diketopyrrolopyrrole wings linked by an acetylene bridge have been synthesized. These derivatives feature two different axial substituents (i. e., 4-tert-butylphenoxy (OPh) or chlorine (Cl)) and for each of them, both the C-1 and the C-3 regioisomers have been investigated. The four compounds exhibit a broad absorption band in the 450-700 nm region, with bandgap values near to 2 eV. These materials were applied in the active layer of inverted bulk-heterojunction polymer solar cells in combination with the donor polymer PBDB-T. Derivatives bearing the OPh axial group showed the best performances, with C-1-OPh being the most promising with a PCE of 3.27 % and a V-oc as high as 1.17 V. Despite presenting the widest absorption range, the photovoltaic results obtained with C-1-Cl turned out to be the lowest (PCE=1.01 %). |
| DOI de l'article: | 10.1002/cplu.202100103 |
| Enllaç font original: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cplu.202100103 |
| Versió de l'article dipositat: | info:eu-repo/semantics/publishedVersion |
| Accès a la llicència d'ús: | https://creativecommons.org/licenses/by/3.0/es/ |
| Departament: | Enginyeria Electrònica, Elèctrica i Automàtica |
| URL Document de llicència: | https://repositori.urv.cat/ca/proteccio-de-dades/ |
| Àrees temàtiques: | Chemistry (all) Chemistry (miscellaneous) Chemistry, multidisciplinary General chemistry Química |
| Paraules clau: | π -systems boron subphthalocyanines core efficient infinity-systems interface non-fullerene acceptor organic solar cells performance subphthalocyanines π -systems Boron subphthalocyanines Core Diketopyrrolopyrroles Efficient Hole-transport layer Infinity-systems Interface Non-fullerene acceptor Organic solar cells Performance Subphthalocyanine Subphthalocyanines Π-systems |
| Entitat: | Universitat Rovira i Virgili |
| Data d'alta del registre: | 2024-10-12 |
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