Articles producció científica> Química Analítica i Química Orgànica

HPLC-UV and HPLC-CAD chromatographic data fusion for the authentication of the geographical origin of palm oil

  • Dades identificatives

    Identificador: PC:2802
    Autors:
    Ruisánchez, I.Obisesan, K.A.Jiménez-Carvelo, A.M.Cuadros-Rodriguez, L.Callao, M.P.
    Resum:
    Filiació URV: SI
  • Altres:

    Autor segons l'article: Ruisánchez, I.; Obisesan, K.A.; Jiménez-Carvelo, A.M.; Cuadros-Rodriguez, L.; Callao, M.P.
    Departament: Química Analítica i Química Orgànica
    Autor/s de la URV: RUISANCHEZ CAPELASTEGUI, MARÍA ICIAR; Obisesan, K.A.; Jiménez-Carvelo, A.M.; Cuadros-Rodriguez, L.; CALLAO LASMARIAS, MARÍA PILAR
    Paraules clau: authentication Data Fusion Liquid Chromatography
    Resum: Data fusion combined with a multivariate classification approach (partial least squares-discriminant analysis, PLS-DA) was applied to authenticate the geographical origin of palm oil. Data fusion takes advantage of the synergistic effect of information collected from more than one data source. In this study, data from liquid chromatography coupled to two detectors –ultraviolet (UV) and charged aerosol (CAD)– was fused by high- and mid-level data fusion strategies. Mid-level data fusion combines a few variables from each technique and then applies the classification technique. Principal component analysis and interval partial least squares were applied to obtain the variables selected. High-level data fusion combines the PLS-DA classification results obtained individually from the chromatographic technique with each detector. Fuzzy aggregation connective operators were used to make the combinations. Prediction rates varied between 73% and 98% for the individual techniques and between 87% and 100% and 93% and 100% for the mid- and high-level data fusion strategies, respectively.
    Grup de recerca: Grup de Quimiometria, Qualimetria i Nanosensors
    Àrees temàtiques: Química Química Chemistry
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0039-9140
    Identificador de l'autor: 0000-0002-7097-3583; n/a; n/a; n/a; 0000-0003-2691-329X
    Data d'alta del registre: 2017-05-18
    Pàgina final: 418
    Volum de revista: 170
    Versió de l'article dipositat: info:eu-repo/semantics/submittedVersion
    Enllaç font original: http://www.sciencedirect.com/science/article/pii/S0039914017304563
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.1016/j.talanta.2017.04.035
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2017
    Pàgina inicial: 413
    Tipus de publicació: Article Artículo Article
  • Paraules clau:

    Cromatografia de líquids
    authentication
    Data Fusion
    Liquid Chromatography
    Química
    Química
    Chemistry
    0039-9140
  • Documents:

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