Articles producció científica> Química Analítica i Química Orgànica

Different sample treatments for the determination of ICM-XR in fish samples followed by LC-HRMS

  • Dades identificatives

    Identificador: PC:3165
    Autors:
    Borrull, F.Nuñez, M.Fontanals, N.Pocurull, E.
    Resum:
    Filiació URV: SI
  • Altres:

    Autor segons l'article: Borrull, F. ; Nuñez, M.; Fontanals, N. ; Pocurull, E.
    Departament: Química Analítica i Química Orgànica
    Autor/s de la URV: BORRULL BALLARÍN, FRANCESC; Nuñez, M.; Fontanals, N. ; POCURULL AIXALA, EVA
    Paraules clau: High resolution mass spectrometry Pressurised liquid extraction IODINATED X-RAY CONTRAST MEDIA
    Resum: Iodinated X-ray contrast media (ICM-XR) are a group of pharmaceuticals widely used in medicine. Due to their ow biodegradation rate, which makes their removal at wastewater treatment plants difficult, and the high doses at which they are administered, they have been detected in aquatic environments. In the present paper, a method for the quantitative determination of a group of ICM-XR in different fish species was developed and validated for the first time. Two extraction techniques were compared: pressurised liquid extraction (PLE) and QuECh- ERS (Quick, Easy, Cheap, Effective, Rugged and Safe), with PLE being selected, followed by liquid chromatography-high resolution mass spectrometry. In addition, several clean-up strategies were evaluated. The optimised method provided PLE recoveries ranging from 60% to 88% and limits of detection ranging from 5 ng/g to 25 ng/g (dry weight). The method was applied in order to evaluate the presence of the selected ICM-XR in different fish species.
    Grup de recerca: Grup de Cromatografia. Aplicacions Mediambientals
    Àrees temàtiques: Chemistry Química Química
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0039-9140
    Identificador de l'autor: 0000-0003-2718-9336; ; ; 0000-0001-5123-995X
    Data d'alta del registre: 2018-03-05
    Pàgina final: 7
    Volum de revista: 163
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://www.sciencedirect.com/science/article/pii/S0039914016308669?via%3Dihub
    Programa de finançament: plan; CTQ 2014-52617-P) plan; CTQ2011-24179
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.1016/j.talanta.2016.11.004
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2017
    Pàgina inicial: 1
    Tipus de publicació: Article Artículo Article
  • Paraules clau:

    Cromatografia de líquids d'alta resolució
    Peix--Contaminació
    Espectrometria de masses
    High resolution mass spectrometry
    Pressurised liquid extraction
    IODINATED X-RAY CONTRAST MEDIA
    Chemistry
    Química
    Química
    0039-9140
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