Autor segons l'article: Fontanals, N.; Núñez, M.; Borrull, F.; Pocurull, E.
Departament: Química Analítica i Química Orgànica
Autor/s de la URV: FONTANALS TORROJA, NÚRIA; Núñez, M.; Borrull, F.; Pocurull, E.
Resum: An analytical method based on pressurized liquid extraction (PLE) followed by liquid chromatography-high resolution mass spectrometry (Orbitrap) was developed for the simultaneous determination of ten high-intensity sweeteners in fish samples. As the method was developed, the different PLE parameters were optimized and different clean-up strategies were evaluated, of which in-cell clean-up using alumina and on-cell clean-up with hexane were the most effective. PLE recoveries were between 43% and 94%. The limits of quantification were between 12.5 ng g-1 dry weight (d.w.) and 250 ng g-1 (d.w.) and the limits of detection between 2.5 ng g-1 (d.w.) and 125 ng g-1 (d.w.). Intra-day precision and inter-day precision were below 16% and 25%, respectively. Fish samples from different species were analysed and, saccharin was found below its limit of quantification in the species Scomber scombrus.
Grup de recerca: Grup de Cromatografia. Aplicacions Mediambientals
Àrees temàtiques: Química Química Chemistry
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0021-9673
Identificador de l'autor: 0000-0002-7534-1964; ; ;
Data d'alta del registre: 2019-01-18
Pàgina final: 39
Volum de revista: 1479
Versió de l'article dipositat: info:eu-repo/semantics/submittedVersion
Enllaç font original: https://www.sciencedirect.com/science/article/abs/pii/S0021967316316211?via%3Dihub
DOI de l'article: 10.1016/j.chroma.2016.12.006
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2016
Pàgina inicial: 32
Tipus de publicació: Article Artículo Article
Repositori URV