Articles producció científica> Química Física i Inorgànica

Hydrophobic Effect as a Driving Force for Host-Guest Chemistry of a Multi-Receptor Keplerate-Type Capsule

  • Dades identificatives

    Identificador: imarina:5128852
    Autors:
    Watfa, NancyMelgar, DoloresHaouas, MohamedTaulelle, FrancisHijazi, AkramNaoufal, DaoudAvalos, Josep BonetFloquet, SebastienBo, CarlesCadot, Emmanuel
    Resum:
    The effectiveness of the interactions between various alkylammonium cations and the well-defined spherical Keplerate-type {Mo132} capsule has been tracked by 1H DOSY NMR methodology, revealing a strong dependence on the self-diffusion coefficient of the cationic guests balanced between the solvated and the plugging situations. Analysis of the data is fully consistent with a two-site exchange regime involving the 20 independent {Mo9O9} receptors of the capsule. Furthermore, quantitative analysis allowed us to determine the stability constants associated with the plugging process of the pores. Surprisingly, the affinity of the capsule for a series of cationic guests increases continuously with its apolar character, as shown by the significant change of the stability constant from 370 to 6500 for NH4+ and NEt4+, respectively. Such observations, supported by the thermodynamic parameters, evidence that the major factor dictating selectivity in the trapping process is the so-called hydrophobic effect. Computational studies, using molecular dynamics simulations, have been carried out in conjunction with the experiments. Analysis of the radial distribution functions g(r) reveals that NH4+ and NMe4+ ions behave differently in the vicinity of the capsule. The NH4+ ions do not exhibit well-defined distributions when in close vicinity. In contrast, the NMe4+ ions displayed sharp distributions related to different scenarios, such as firmly trapped or labile guest facing the {Mo9O9} pores. Together, these experimental and theoretical insights should aid in the exploitation of these giant polyoxometalates in solution for various applications. © 2015 American Chemical Society.
  • Altres:

    Autor segons l'article: Watfa, Nancy; Melgar, Dolores; Haouas, Mohamed; Taulelle, Francis; Hijazi, Akram; Naoufal, Daoud; Avalos, Josep Bonet; Floquet, Sebastien; Bo, Carles; Cadot, Emmanuel;
    Departament: Química Física i Inorgànica Enginyeria Química
    Autor/s de la URV: Bo Jané, Carles / Bonet Avalos, José
    Paraules clau: Diffusion in liquids Diffusion Computational chemistry
    Resum: The effectiveness of the interactions between various alkylammonium cations and the well-defined spherical Keplerate-type {Mo132} capsule has been tracked by 1H DOSY NMR methodology, revealing a strong dependence on the self-diffusion coefficient of the cationic guests balanced between the solvated and the plugging situations. Analysis of the data is fully consistent with a two-site exchange regime involving the 20 independent {Mo9O9} receptors of the capsule. Furthermore, quantitative analysis allowed us to determine the stability constants associated with the plugging process of the pores. Surprisingly, the affinity of the capsule for a series of cationic guests increases continuously with its apolar character, as shown by the significant change of the stability constant from 370 to 6500 for NH4+ and NEt4+, respectively. Such observations, supported by the thermodynamic parameters, evidence that the major factor dictating selectivity in the trapping process is the so-called hydrophobic effect. Computational studies, using molecular dynamics simulations, have been carried out in conjunction with the experiments. Analysis of the radial distribution functions g(r) reveals that NH4+ and NMe4+ ions behave differently in the vicinity of the capsule. The NH4+ ions do not exhibit well-defined distributions when in close vicinity. In contrast, the NMe4+ ions displayed sharp distributions related to different scenarios, such as firmly trapped or labile guest facing the {Mo9O9} pores. Together, these experimental and theoretical insights should aid in the exploitation of these giant polyoxometalates in solution for various applications. © 2015 American Chemical Society.
    Àrees temàtiques: Química Materiais Interdisciplinar General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Colloid and surface chemistry Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biochemistry Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: carles.bo@urv.cat josep.bonet@urv.cat
    Identificador de l'autor: 0000-0001-9581-2922 0000-0002-7339-9564
    Data d'alta del registre: 2024-09-07
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://pubs.acs.org/doi/10.1021/jacs.5b01526
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Journal Of The American Chemical Society. 137 (17): 5845-5851
    Referència de l'ítem segons les normes APA: Watfa, Nancy; Melgar, Dolores; Haouas, Mohamed; Taulelle, Francis; Hijazi, Akram; Naoufal, Daoud; Avalos, Josep Bonet; Floquet, Sebastien; Bo, Carles; (2015). Hydrophobic Effect as a Driving Force for Host-Guest Chemistry of a Multi-Receptor Keplerate-Type Capsule. Journal Of The American Chemical Society, 137(17), 5845-5851. DOI: 10.1021/jacs.5b01526
    DOI de l'article: 10.1021/jacs.5b01526
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2015
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Biochemistry,Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Colloid and Surface Chemistry
    Diffusion in liquids
    Diffusion
    Computational chemistry
    Química
    Materiais
    Interdisciplinar
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Colloid and surface chemistry
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Biochemistry
    Astronomia / física
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