Articles producció científica> Enginyeria Electrònica, Elèctrica i Automàtica

Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors

  • Dades identificatives

    Identificador: imarina:5133104
    Autors:
    Casanova-Chafer, Juan Bittencourt, Carla Llobet, Eduard
    Resum:
    © 2019 Casanova-Cháfer et al. Here we describe the development of chemoresistive sensors employing oxygen-plasma-treated, Au-decorated multiwall carbon nanotubes (MWCNTs) functionalized with self-assembled monolayers (SAMs) of thiols. For the first time, the effects of the length of the carbon chain and its hydrophilicity on the gas sensing properties of SAMs formed on carbon nanotubes are studied, and additionally, the gas sensing mechanisms are discussed. Four thiols differing in the length of the carbon chain and in the hydrophobic or hydrophilic nature of the head functional group are studied. Transmission electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy are used to analyze the resulting gas-sensitive hybrid films. Among the different nanomaterials tested, short-chain thiols having a hydrophilic head group, self-assembled onto Au-decorated carbon nanotubes were most responsive to nitrogen dioxide and ethanol vapors, even in the presence of ambient humidity. In particular, this nanomaterial was about eight times more sensitive to nitrogen dioxide than bare Au-decorated carbon nanotubes when operated at room temperature. This response enhancement is attributed to the interaction, via strong hydrogen bonding, of the polar molecules tested to the polar surface of hydrophilic thiols. The approach discussed here could be extended further by combining hydrophilic and hydrophobic thiol SAMs in Au-MWCNT sensor arrays as a helpful strategy for tuning sensor response and selectivity. This would make the detection of polar and nonpolar gas species employing low-power gas sensors easier, even under fluctuating ambient moisture conditions.
  • Altres:

    Autor segons l'article: Casanova-Chafer, Juan Bittencourt, Carla Llobet, Eduard
    Departament: Enginyeria Electrònica, Elèctrica i Automàtica
    Autor/s de la URV: Llobet Valero, Eduard
    Paraules clau: Vapor Thiol Sensitivity Self-assembled monolayer (sam) Percolation Nitrogen-dioxide Networks Multiwall carbon nanotubes (mwcnts) Hydrophobicity Hydrophilicity Gas sensing mechanism Films Carbon length chain Au self-assembled monolayer (sam) multiwall carbon nanotubes (mwcnts) hydrophobicity hydrophilicity gas sensing mechanism carbon length chain
    Resum: © 2019 Casanova-Cháfer et al. Here we describe the development of chemoresistive sensors employing oxygen-plasma-treated, Au-decorated multiwall carbon nanotubes (MWCNTs) functionalized with self-assembled monolayers (SAMs) of thiols. For the first time, the effects of the length of the carbon chain and its hydrophilicity on the gas sensing properties of SAMs formed on carbon nanotubes are studied, and additionally, the gas sensing mechanisms are discussed. Four thiols differing in the length of the carbon chain and in the hydrophobic or hydrophilic nature of the head functional group are studied. Transmission electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy are used to analyze the resulting gas-sensitive hybrid films. Among the different nanomaterials tested, short-chain thiols having a hydrophilic head group, self-assembled onto Au-decorated carbon nanotubes were most responsive to nitrogen dioxide and ethanol vapors, even in the presence of ambient humidity. In particular, this nanomaterial was about eight times more sensitive to nitrogen dioxide than bare Au-decorated carbon nanotubes when operated at room temperature. This response enhancement is attributed to the interaction, via strong hydrogen bonding, of the polar molecules tested to the polar surface of hydrophilic thiols. The approach discussed here could be extended further by combining hydrophilic and hydrophobic thiol SAMs in Au-MWCNT sensor arrays as a helpful strategy for tuning sensor response and selectivity. This would make the detection of polar and nonpolar gas species employing low-power gas sensors easier, even under fluctuating ambient moisture conditions.
    Àrees temàtiques: Química Physics, applied Physics and astronomy (miscellaneous) Physics and astronomy (all) Nanoscience and nanotechnology Nanoscience & nanotechnology Materials science, multidisciplinary Materials science (miscellaneous) Materials science (all) Interdisciplinar General physics and astronomy General materials science Engenharias iv Engenharias iii Electrical and electronic engineering Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 21904286
    Adreça de correu electrònic de l'autor: eduard.llobet@urv.cat
    Identificador de l'autor: 0000-0001-6164-4342
    Data d'alta del registre: 2023-02-18
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://www.beilstein-journals.org/bjnano/articles/10/58
    Referència a l'article segons font original: Beilstein Journal Of Nanotechnology. 10 565-577
    Referència de l'ítem segons les normes APA: Casanova-Chafer, Juan Bittencourt, Carla Llobet, Eduard (2019). Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors. Beilstein Journal Of Nanotechnology, 10(), 565-577. DOI: 10.3762/bjnano.10.58
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.3762/bjnano.10.58
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2019
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Electrical and Electronic Engineering,Materials Science (Miscellaneous),Materials Science, Multidisciplinary,Nanoscience & Nanotechnology,Nanoscience and Nanotechnology,Physics and Astronomy (Miscellaneous),Physics, Applied
    Vapor
    Thiol
    Sensitivity
    Self-assembled monolayer (sam)
    Percolation
    Nitrogen-dioxide
    Networks
    Multiwall carbon nanotubes (mwcnts)
    Hydrophobicity
    Hydrophilicity
    Gas sensing mechanism
    Films
    Carbon length chain
    Au
    self-assembled monolayer (sam)
    multiwall carbon nanotubes (mwcnts)
    hydrophobicity
    hydrophilicity
    gas sensing mechanism
    carbon length chain
    Química
    Physics, applied
    Physics and astronomy (miscellaneous)
    Physics and astronomy (all)
    Nanoscience and nanotechnology
    Nanoscience & nanotechnology
    Materials science, multidisciplinary
    Materials science (miscellaneous)
    Materials science (all)
    Interdisciplinar
    General physics and astronomy
    General materials science
    Engenharias iv
    Engenharias iii
    Electrical and electronic engineering
    Astronomia / física
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