Autor segons l'article: Perez, Aaron; Lligadas, Gerard; Ronda, Juan Carlos; Galia, Marina; Cadiz, Virginia
Departament: Química Analítica i Química Orgànica
Autor/s de la URV: Cádiz Deleito, Maria Virginia / Galià Clua, Marina Teresa / Lligadas Puig, Gerard / PÉREZ DÍAZ, ANA MARÍA / Ronda Bargalló, Juan Carlos
Paraules clau: Transfer radical polymerization; Thermogravimetric analysis; Ring-opening polymerization; Ring opening polymerization; Renewable resources; Renewable resource; Polytrimethylene carbonate; Poly (trimethylene carbonate); Metal-free atrp; Metal-free atom transfer radical polymerization; Metal free; Free atoms; Differential scanning calorimetry; Diels-alder reaction; Crosslinking; Carbonation; Block copolymers; Block co polymers; Atom-transfer radical polymerization; Atom transfer radical polymerization; thermal-degradation; renewable resources; raft polymerization; networks; metal-free atrp; diels-alder reaction; bearing; aba triblock copolymer
Resum: Block copolymers containing poly(trimethylene carbonate) (PTMC) middle block and poly(furfuryl methacrylate) PFMA end blocks were synthesized through sequential organocatalytic ring opening polymerization (ROP) of trimethylene carbonate and thermal and photoinitiated metal-free atom transfer radical polymerizations (ATRP) of furfuryl methacrylate. The thermal and mechanical properties of the triblock copolymers were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamical mechanical analysis (DMA). The crosslinking via Diels-Alder (DA) reaction between the furan groups of the block copolymers and bismaleimide and bisitaconimide was proved by FTIR and DSC and the thermoreversibility properties of the crosslinked polymer were subsequently investigated using DSC and solubility testing. © 2021 Elsevier Ltd
Àrees temàtiques: Química; Polymers and plastics; Polymer science; Physics and astronomy (miscellaneous); Physics and astronomy (all); Organic chemistry; Odontología; Materials chemistry; Materiais; Interdisciplinar; General physics and astronomy; Farmacia; Engenharias iv; Engenharias iii; Engenharias ii; Engenharias i; Ciências ambientais; Ciência de alimentos; Ciência da computação; Biotecnología; Astronomia / física; Arquitetura, urbanismo e design
Adreça de correu electrònic de l'autor: marina.galia@urv.cat; juancarlos.ronda@urv.cat; gerard.lligadas@urv.cat
Data d'alta del registre: 2025-01-08
Enllaç font original: https://www.sciencedirect.com/science/article/pii/S0014305721006078?via%3Dihub
Referència a l'article segons font original: European Polymer Journal. 162 110873-
Referència de l'ítem segons les normes APA: Perez, Aaron; Lligadas, Gerard; Ronda, Juan Carlos; Galia, Marina; Cadiz, Virginia (2022). Thermoreversible poly(trimethylene carbonate)-based block copolymers containing reactive furfuryl groups via sequential ROP and ATRP. European Polymer Journal, 162(), 110873-. DOI: 10.1016/j.eurpolymj.2021.110873
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
DOI de l'article: 10.1016/j.eurpolymj.2021.110873
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2022
Tipus de publicació: Journal Publications
Repositori URV