Articles producció científica> Química Física i Inorgànica

Iron(III) versatile catalysts for cycloaddition of CO2 to epoxides and epoxidation of alkenes

  • Identification data

    Identifier: PC:2702
    Authors:
    Cuesta-Aluja, L.Masdeu-Bultó, A.M.
    Abstract:
    Fe(III) complexes with tridentate pyridine-imine-phenolato ligands differing in the chain length between the imine and pyridine groups (2-methylpyridine L1 and 2-ethylpyridine L2) have been synthesized. New complex [Fe(L2)2]ClO4 (2) was characterized by X-ray diffraction and spectroscopic techniques. [Fe(L1)2]ClO4 (1) and 2 form active catalysts for the cycloaddition of CO2 to epoxides and for the epoxidation of alkenes. Catalytic systems with the more flexible skeleton (2) in combination with tetrabutylammonium bromide (TBAB) were more active than 1/TBAB in the cycloaddition of CO2 to epoxides. TOFs up to 900 h−1 for the selective synthesis of styrene carbonate and 3640 h−1 for the synthesis of glycidol carbonate were obtained using 2/TBAB at low catalyst loadings (0.025 mol %). Additionally, 2 was also active in the epoxidation of styrene derivatives such as trans-stilbene (conversion 88 %) and trans-β-methylstyrene (conversion 100 %) using tert-butylhydroperoxide as oxidant at 60 ºC in acetonitrile. Epoxidation of styrene and cyclohexene proceed at low conversions.
  • Others:

    Author, as appears in the article.: Cuesta-Aluja, L.; Masdeu-Bultó, A.M.
    Department: Química Física i Inorgànica
    URV's Author/s: CUESTA ALUJA, LAIA; MASDEU BULTÓ, ANNA MARIA
    Keywords: Fe(III) catalysis
    Abstract: Fe(III) complexes with tridentate pyridine-imine-phenolato ligands differing in the chain length between the imine and pyridine groups (2-methylpyridine L1 and 2-ethylpyridine L2) have been synthesized. New complex [Fe(L2)2]ClO4 (2) was characterized by X-ray diffraction and spectroscopic techniques. [Fe(L1)2]ClO4 (1) and 2 form active catalysts for the cycloaddition of CO2 to epoxides and for the epoxidation of alkenes. Catalytic systems with the more flexible skeleton (2) in combination with tetrabutylammonium bromide (TBAB) were more active than 1/TBAB in the cycloaddition of CO2 to epoxides. TOFs up to 900 h−1 for the selective synthesis of styrene carbonate and 3640 h−1 for the synthesis of glycidol carbonate were obtained using 2/TBAB at low catalyst loadings (0.025 mol %). Additionally, 2 was also active in the epoxidation of styrene derivatives such as trans-stilbene (conversion 88 %) and trans-β-methylstyrene (conversion 100 %) using tert-butylhydroperoxide as oxidant at 60 ºC in acetonitrile. Epoxidation of styrene and cyclohexene proceed at low conversions.
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Chemistry Química Química
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 2365-6549
    Author identifier: ;
    Record's date: 2017-03-22
    Last page: 2070
    Journal volume: 1
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/slct.201600488/abstract
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1002/slct.201600488
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    First page: 2065
    Publication Type: Article Artículo Article
  • Keywords:

    Catalitzadors
    Anhídrid carbònic
    Fe(III) catalysis
    Chemistry
    Química
    Química
    2365-6549
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