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Hydrophilic interaction liquid chromatography coupled to mass spectrometry-based detection to determine emerging organic contaminants in environmental samples 

  • Identification data

    Identifier: PC:3018
    Authors:
    Borrull, F.Salas, D.Fontanals, N.Marcé, R. M.
    Abstract:
    Hydrophilic interaction liquid chromatography (HILIC) has gained widespread acceptance as an alternative to reversed-phase liquid chromatography (RPLC) for the retention and separation of polar compounds. Because a great number of emerging organic contaminants are polar, this represents progress in terms of solving most of the problems and limitations encountered in the conventional methods developed for their determination. In this review, recent HILIC applications developed in the environmental field are described, which are normally coupled with mass spectrometry, in order to reach the limits required to quantify contaminants present at trace levels and benefit from its capacity for confirmation. Special attention is paid to the stationary and mobile phases commonly used in terms of the advantages that they offer compared to reversed-phase columns and the high-water content mobile phases traditionally used in RPLC. The most important features related to the matrices and contaminants normally studied are also discussed, as well as the contribution of the HILIC mode towards reducing the matrix effect.
  • Others:

    Author, as appears in the article.: Borrull, F. ; Salas, D. ; Fontanals, N. ; Marcé, R. M.
    Department: Química Analítica i Química Orgànica
    URV's Author/s: BORRULL BALLARÍN, FRANCESC; Salas, D. ; Fontanals, N. ; MARCÉ RECASENS, ROSA MARIA
    Keywords: Hydrophilic interaction liquid chromatography mass spectrometry Emerging organic contaminants
    Abstract: Hydrophilic interaction liquid chromatography (HILIC) has gained widespread acceptance as an alternative to reversed-phase liquid chromatography (RPLC) for the retention and separation of polar compounds. Because a great number of emerging organic contaminants are polar, this represents progress in terms of solving most of the problems and limitations encountered in the conventional methods developed for their determination. In this review, recent HILIC applications developed in the environmental field are described, which are normally coupled with mass spectrometry, in order to reach the limits required to quantify contaminants present at trace levels and benefit from its capacity for confirmation. Special attention is paid to the stationary and mobile phases commonly used in terms of the advantages that they offer compared to reversed-phase columns and the high-water content mobile phases traditionally used in RPLC. The most important features related to the matrices and contaminants normally studied are also discussed, as well as the contribution of the HILIC mode towards reducing the matrix effect.
    Research group: Grup de Cromatografia. Aplicacions Mediambientals
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0165-9936
    Author identifier: 0000-0003-2718-9336; ; ; 0000-0002-5667-2899
    Record's date: 2018-02-28
    Last page: 149
    Journal volume: 94
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/pii/S0165993617301231
    Funding program: plan; Excelencia; CTQ2014-52617-P plan; PhD grant; BES-2012-057792
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1016/j.trac.2017.07.017
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    First page: 141
    Publication Type: Article Artículo Article
  • Keywords:

    cromatografia de líquids
    Hydrophilic interaction liquid chromatography
    mass spectrometry
    Emerging organic contaminants
    Química
    Química
    Chemistry
    0165-9936
  • Documents:

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