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Dynamic fabric phase sorptive extraction for a group of pharmaceuticals and personal care products from environmental waters 

  • Identification data

    Identifier: PC:3021
    Authors:
    Borrull, F.Lakade S.Furton, K.Kabir, A.Marcé, R. M.Fontanals, N.
    Abstract:
    This paper describes for the first time the use of a new extraction technique, based on fabric phase sorptive extraction (FPSE). This new mode proposes the extraction of the analytes in dynamic mode in order to reduce the extraction time. Dynamic fabric phase sorptive extraction (DFPSE) followed by liquid chromatography-tandem mass spectrometry was evaluated for the extraction of a group of pharmaceuticals and personal care products (PPCPs) from environmental water samples. Different parameters affecting the extraction were optimized and best conditions were achieved when 50mL of sample at pH 3 was passed through 3 disks and analytes retained were eluted with 10mL of ethyl acetate. The recoveries were higher than 60% for most of compounds with the exception of the most polar ones (between 8% and 38%). The analytical method was validated with environmental samples such as river water and effluent and influent wastewater, and good performance was obtained. The analysis of samples revealed the presence of some PPCPs at low ngL(-1) concentrations.
  • Others:

    Author, as appears in the article.: Borrull, F. ; Lakade S. ; Furton, K. ; Kabir, A. ; Marcé, R. M. ; Fontanals, N.
    Department: Química Analítica i Química Orgànica
    URV's Author/s: BORRULL BALLARÍN, FRANCESC; Lakade S. ; Furton, K. ; Kabir, A. ; MARCÉ RECASENS, ROSA MARIA; Fontanals, N.
    Keywords: Dynamic fabric phase sorptive extraction Liquid chromatography-tandem mass spectrometry pharmaceuticals and personal care products
    Abstract: This paper describes for the first time the use of a new extraction technique, based on fabric phase sorptive extraction (FPSE). This new mode proposes the extraction of the analytes in dynamic mode in order to reduce the extraction time. Dynamic fabric phase sorptive extraction (DFPSE) followed by liquid chromatography-tandem mass spectrometry was evaluated for the extraction of a group of pharmaceuticals and personal care products (PPCPs) from environmental water samples. Different parameters affecting the extraction were optimized and best conditions were achieved when 50mL of sample at pH 3 was passed through 3 disks and analytes retained were eluted with 10mL of ethyl acetate. The recoveries were higher than 60% for most of compounds with the exception of the most polar ones (between 8% and 38%). The analytical method was validated with environmental samples such as river water and effluent and influent wastewater, and good performance was obtained. The analysis of samples revealed the presence of some PPCPs at low ngL(-1) concentrations.
    Research group: Grup de Cromatografia. Aplicacions Mediambientals
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0021-9673
    Author identifier: 0000-0003-2718-9336; ; ; ; 0000-0002-5667-2899;
    Record's date: 2018-03-01
    Last page: 26
    Journal volume: 1456
    Papper version: info:eu-repo/semantics/submittedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0021967316307221?via%3Dihub
    Funding program: plan; CTQ2014-52617-P
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1016/j.chroma.2016.05.097
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    First page: 19
    Publication Type: Article Artículo Article
  • Keywords:

    Cromatografia de líquids
    Extracció (Química)
    Medicaments
    Dynamic fabric phase sorptive extraction
    Liquid chromatography-tandem mass spectrometry
    pharmaceuticals and personal care products
    Química
    Química
    Chemistry
    0021-9673
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