Author, as appears in the article.: Fernández, E. ; León, L.
Department: Química Física i Inorgànica
URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; León, L.
Keywords: Pauson¿Khand reaction alkynylboronic esters
Abstract: The first intermolecular Pauson-Khand reaction conduct-ed with internal alkynylboronic esters has been described. This strategy allows the installation of the boronic ester moiety in ¿-position of the cyclopentenone with total re-gio- and stereoselectivity. More interestingly, the resulting adduct can be subsequently derivatized by Suzuki-Miyaura cross-coupling reaction allowing any combination of ¿,¿-disubstituted cyclopentenones, solving, thus, a well-known and long-standing drawback about regioselectivity in Pauson-Khand reaction
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1359-7345
Author identifier: 0000-0001-9025-1791;
Record's date: 2018-03-08
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: http://pubs.rsc.org/en/content/articlepdf/2016/cc/c6cc04717c
Funding program: plan; Excelencia; CTQ2013-43395-P altres; Acció; TECSPR13-1-0040
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1039/c6cc04717c
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
Publication Type: Article Artículo Article
Repositori URV