Articles producció científica> Infermeria

Gold(I) as an artificial cyclase: Short stereodivergent syntheses of (-)-epiglobulol and (-)-4ß,7a- and (-)-4a,7a- aromadendranediols

  • Identification data

    Identifier: PC:757
  • Authors:

    Carreras, J.
    Livendahl, M.
    McGonigal, P.R.
    Echavarren, A.M.
  • Others:

    Author, as appears in the article.: Carreras, J. Livendahl, M. McGonigal, P.R. Echavarren, A.M.
    Department: Infermeria
    e-ISSN: 1521-3773
    Abstract: Three natural aromadendrane sesquiterpenes, ()- epiglobulol, ()-4b,7a-aromadendranediol, and ()-4a,7aaromadendranediol, have been synthesized in only seven steps in 12, 15, and 17% overall yields, respectively, from (E,E)- farnesol by a stereodivergent gold(I)-catalyzed cascade reaction which forms the tricyclic aromadendrane core in a single step. These are the shortest total syntheses of these natural compounds.
    licence for use:
    ISSN: 1433-7851
    Last page: 4899
    Journal volume: 53
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: http://jsessionid=8B1A936DF1C0FB172343853DF5EEFA67.f03t03 /
    Article's DOI: 10.1002/anie.201402044
    Entity: Universitat Rovira i Virgili.
    Journal publication year: 2014
    First page: 4896