Articles producció científicaInfermeria

Gold(I) as an artificial cyclase: Short stereodivergent syntheses of (-)-epiglobulol and (-)-4ß

  • Identification data

    Identifier:  PC:757
    Handle: https://hdl.handle.net/20.500.11797/PC757
    Authors:  Carreras, J.; Livendahl, M.; McGonigal, P.R.; Echavarren, A.M.
    Abstract:
    Three natural aromadendrane sesquiterpenes, ()- epiglobulol, ()-4b,7a-aromadendranediol, and ()-4a,7aaromadendranediol, have been synthesized in only seven steps in 12, 15, and 17% overall yields, respectively, from (E,E)- farnesol by a stereodivergent gold(I)-catalyzed cascade reaction which forms the tricyclic aromadendrane core in a single step. These are the shortest total syntheses of these natural compounds.

  • Others:

    Link to the original source: http://jsessionid=8B1A936DF1C0FB172343853DF5EEFA67.f03t03 / http://onlinelibrary.wiley.com/doi/10.1002/anie.201402044/abstract
    Article's DOI: 10.1002/anie.201402044
    Journal publication year: 2014
    Entity: Universitat Rovira i Virgili.
    Paper version: info:eu-repo/semantics/publishedVersion
    First page: 4896
    Department: Infermeria
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Last page: 4899
    ISSN: 1433-7851
    Author, as appears in the article.: Carreras, J., Livendahl, M., McGonigal, P.R., Echavarren, A.M.
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Journal volume: 53
    e-ISSN: 1521-3773