Articles producció científica> Infermeria

Gold(I) as an artificial cyclase: Short stereodivergent syntheses of (-)-epiglobulol and (-)-4ß,7a- and (-)-4a,7a- aromadendranediols

  • Identification data

    Identifier: PC:757
    Handle: https://hdl.handle.net/20.500.11797/PC757
    Authors:
    Carreras, J.Livendahl, M.McGonigal, P.R.Echavarren, A.M.
    Abstract:
    10.1002/anie.201402044

  • Others:

    Author, as appears in the article.: Carreras, J. Livendahl, M. McGonigal, P.R. Echavarren, A.M.
    Department: Infermeria
    e-ISSN: 1521-3773
    Abstract: Three natural aromadendrane sesquiterpenes, ()- epiglobulol, ()-4b,7a-aromadendranediol, and ()-4a,7aaromadendranediol, have been synthesized in only seven steps in 12, 15, and 17% overall yields, respectively, from (E,E)- farnesol by a stereodivergent gold(I)-catalyzed cascade reaction which forms the tricyclic aromadendrane core in a single step. These are the shortest total syntheses of these natural compounds.
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1433-7851
    Last page: 4899
    Journal volume: 53
    Paper version: info:eu-repo/semantics/publishedVersion
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Entity: Universitat Rovira i Virgili.
    Journal publication year: 2014
    First page: 4896