Author, as appears in the article.: Cuenca, Ana B; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena
Department: Química Física i Inorgànica
URV's Author/s: Fernández Gutiérrez, Maria Elena / Fernández López, Elena
Keywords: Unsaturated-compounds Transition-metal-free b-b Terminal alkynes N-heterocyclic carbenes Iminium ion generators Free borylation Diboron tetrachloride Catalyzed diboration Boron conjugate addition Bond formation Acyclic alpha,beta-unsaturated carbonyls Activation modes
Abstract: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of B-B and B-interelement bonds, as well as the generation of new C-B and C-interelement bonds, in a selective way. The greener consequences of these novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidence that supports the innovative theories are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field.
Thematic Areas: Química Materiais General medicine General chemistry Ciências biológicas ii Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Antropologia / arqueologia
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14604744
Author's mail: mariaelena.fernandez@urv.cat
Author identifier: 0000-0001-9025-1791
Record's date: 2024-11-09
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2017/cs/c6cs00692b#!divAbstract
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemical Society Reviews. 46 (2): 415-430
APA: Cuenca, Ana B; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena (2017). Transition-metal-free B-B and B-interelement reactions with organic molecules. Chemical Society Reviews, 46(2), 415-430. DOI: 10.1039/c6cs00692b
Article's DOI: 10.1039/c6cs00692b
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
Publication Type: Journal Publications
Repositori URV