Articles producció científica> Química Física i Inorgànica

Opportune gem-silylborylation of carbonyl compounds: a modular and stereocontrolled entry to tetrasubstituted olefins

  • Identification data

    Identifier: imarina:3658141
    Authors:
    La Cascia, EnricoCuenca, Ana B.Fernandez, Elena
    Abstract:
    An easy access to highly versatile gem-silylboro-nate synthons is achieved by means of an new olefination reagent, HC(B pin)2(SiMe3). Subsequent silicon or boron-based selective functionalization allows for the modular and stereocontrolled synthesis of all-carbon tetrasubstitut-ed alkenes.Aparticular attraction of this approach is the iodode silylation reaction, whichbecomes apivotaltool for C-Si functionalization.
  • Others:

    Author, as appears in the article.: La Cascia, Enrico; Cuenca, Ana B.; Fernandez, Elena;
    Department: Química Física i Inorgànica
    URV's Author/s: Fernández Gutiérrez, Maria Elena
    Keywords: Tamoxifen Iododesilylation Insertion Gem-silylborylation Alkenes iododesilylation insertion gem-silylborylation alkenes
    Abstract: An easy access to highly versatile gem-silylboro-nate synthons is achieved by means of an new olefination reagent, HC(B pin)2(SiMe3). Subsequent silicon or boron-based selective functionalization allows for the modular and stereocontrolled synthesis of all-carbon tetrasubstitut-ed alkenes.Aparticular attraction of this approach is the iodode silylation reaction, whichbecomes apivotaltool for C-Si functionalization.
    Thematic Areas: Química Organic chemistry Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biotecnología Biodiversidade Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: mariaelena.fernandez@urv.cat
    Author identifier: 0000-0001-9025-1791
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201604782
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Chemistry-A European Journal. 22 (52): 18737-18741
    APA: La Cascia, Enrico; Cuenca, Ana B.; Fernandez, Elena; (2016). Opportune gem-silylborylation of carbonyl compounds: a modular and stereocontrolled entry to tetrasubstituted olefins. Chemistry-A European Journal, 22(52), 18737-18741. DOI: 10.1002/chem.201604782
    Article's DOI: 10.1002/chem.201604782
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    Publication Type: Journal Publications
  • Keywords:

    Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Organic Chemistry
    Tamoxifen
    Iododesilylation
    Insertion
    Gem-silylborylation
    Alkenes
    iododesilylation
    insertion
    gem-silylborylation
    alkenes
    Química
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física
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