Author, as appears in the article.: La Cascia, Enrico; Cuenca, Ana B.; Fernandez, Elena;
Department: Química Física i Inorgànica
URV's Author/s: Fernández Gutiérrez, Maria Elena
Keywords: Tamoxifen Iododesilylation Insertion Gem-silylborylation Alkenes iododesilylation insertion gem-silylborylation alkenes
Abstract: An easy access to highly versatile gem-silylboro-nate synthons is achieved by means of an new olefination reagent, HC(B pin)2(SiMe3). Subsequent silicon or boron-based selective functionalization allows for the modular and stereocontrolled synthesis of all-carbon tetrasubstitut-ed alkenes.Aparticular attraction of this approach is the iodode silylation reaction, whichbecomes apivotaltool for C-Si functionalization.
Thematic Areas: Química Organic chemistry Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biotecnología Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: mariaelena.fernandez@urv.cat
Author identifier: 0000-0001-9025-1791
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemistry-A European Journal. 22 (52): 18737-18741
APA: La Cascia, Enrico; Cuenca, Ana B.; Fernandez, Elena; (2016). Opportune gem-silylborylation of carbonyl compounds: a modular and stereocontrolled entry to tetrasubstituted olefins. Chemistry-A European Journal, 22(52), 18737-18741. DOI: 10.1002/chem.201604782
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
Publication Type: Journal Publications
Repositori URV