Articles producció científicaQuímica Física i Inorgànica

Opportune gem-silylborylation of carbonyl compounds: a modular and stereocontrolled entry to tetrasubstituted olefins

  • Identification data

    Identifier:  imarina:3658141
    Handle: https://hdl.handle.net/20.500.11797/imarina3658141
    Authors:  La Cascia, Enrico; Cuenca, Ana B; Fernandez, Elena
    Abstract:
    An easy access to highly versatile gem-silylboro-nate synthons is achieved by means of an new olefination reagent, HC(B pin)2(SiMe3). Subsequent silicon or boron-based selective functionalization allows for the modular and stereocontrolled synthesis of all-carbon tetrasubstitut-ed alkenes.Aparticular attraction of this approach is the iodode silylation reaction, whichbecomes apivotaltool for C-Si functionalization.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201604782
    APA: La Cascia, Enrico; Cuenca, Ana B; Fernandez, Elena (2016). Opportune gem-silylborylation of carbonyl compounds: a modular and stereocontrolled entry to tetrasubstituted olefins. Chemistry-A European Journal, 22(52), 18737-18741. DOI: 10.1002/chem.201604782
    Paper original source: Chemistry-A European Journal. 22 (52): 18737-18741
    Article's DOI: 10.1002/chem.201604782
    Journal publication year: 2016
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2025-02-18
    URV's Author/s: Fernández Gutiérrez, Maria Elena
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: La Cascia, Enrico; Cuenca, Ana B; Fernandez, Elena
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Organic chemistry, Medicina i, Materiais, Interdisciplinar, General medicine, General chemistry, Farmacia, Engenharias iii, Engenharias ii, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Ciências agrárias i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Biotecnología, Biodiversidade, Astronomia / física
    Author's mail: mariaelena.fernandez@urv.cat

  • Keywords:

    Tamoxifen
    Iododesilylation
    Insertion
    Gem-silylborylation
    Alkenes
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Organic Chemistry
    Química
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry (all)
    Biotecnología
    Biodiversidade
    Astronomia / física

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