Articles producció científicaQuímica Física i Inorgànica

Opportune gem-silylborylation of carbonyl compounds: a modular and stereocontrolled entry to tetrasubstituted olefins

  • Identification data

    Identifier:  imarina:3658141
    Handle: https://hdl.handle.net/20.500.11797/imarina3658141
    Authors:  La Cascia, E; Cuenca, AB; Fernández, E
    Abstract:
    An easy access to highly versatile gem-silylboro-nate synthons is achieved by means of an new olefination reagent, HC(B pin)2(SiMe3). Subsequent silicon or boron-based selective functionalization allows for the modular and stereocontrolled synthesis of all-carbon tetrasubstitut-ed alkenes.Aparticular attraction of this approach is the iodode silylation reaction, whichbecomes apivotaltool for C-Si functionalization.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201604782
    APA: La Cascia, E; Cuenca, AB; Fernández, E (2016). Opportune gem-silylborylation of carbonyl compounds: a modular and stereocontrolled entry to tetrasubstituted olefins. Chemistry-A European Journal, 22(52), 18737-18741. DOI: 10.1002/chem.201604782
    Paper original source: Chemistry-A European Journal. 22 (52): 18737-18741
    Article's DOI: 10.1002/chem.201604782
    Journal publication year: 2016-12-23
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2026-05-09
    URV's Author/s: Fernández Gutiérrez, Maria Elena
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: La Cascia, E; Cuenca, AB; Fernández, E
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Organic chemistry, General medicine, General chemistry, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Biotecnología, Biodiversidade
    Author's mail: mariaelena.fernandez@urv.cat, mariaelena.fernandez@urv.cat

  • Keywords:

    Tamoxifen
    Iododesilylation
    Insertion
    Gem-silylborylation
    Alkenes
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Organic Chemistry
    General medicine
    General chemistry
    Chemistry (all)
    Biotecnología
    Biodiversidade

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