Author, as appears in the article.: Guzman, Dailyn; Ramis, Xavier; Fernandez-Francos, Xavier; De la Flor, Silvia; Serra, Angels
Department: Química Analítica i Química Orgànica; Enginyeria Mecànica
URV's Author/s: De la Flor Lopez, Silvia / Fernández Francos, Xavier / Serra Albet, Maria Angels
Keywords: Thermosets; Structure-property relation; Resins; Renewable resources; Oil; Kinetics; Crosslinking; Clove; Biopolymers; Antioxidant activity; Acid
Abstract: A new triglycidyl eugenol derivative (3EPO-EU) was synthesized and characterized by spectroscopic techniques, and used as starting monomer in the preparation of novel bio-based thiol-epoxy thermosets. As thiols, commercially available tetrathiol derived from pentaerythritol (PETMP), a trithiol derived from eugenol (3SH-EU) and the hexathiol derived from squalene (6SH-SQ) were used in the presence of 4-(N,N-dimethylamino)pyridine as the basic catalyst. A flexible diglycidyl ether derived from hexanediol (2EPO-HEX) was also introduced in order to enhance conversion in formulations containing 6SH-SQ. The evolution of the curing was monitored by differential scanning calorimetry. The materials obtained are rigid at room temperature and showed Tgs up to 103 °C. The thermal stability, thermomechanical and mechanical properties were evaluated and discussed in terms of the structural characteristics of the resulting materials.
Thematic Areas: Surfaces, coatings and films; Química; Organic chemistry; Materials science, coatings & films; Materials chemistry; Materiais; Interdisciplinar; General chemical engineering; Engenharias iv; Engenharias iii; Engenharias ii; Chemistry, applied; Chemical engineering (miscellaneous); Chemical engineering (all)
ISSN: 03009440
Author's mail: angels.serra@urv.cat; xavier.fernandez@urv.cat; silvia.delaflor@urv.cat
Last page: 267
Record's date: 2024-11-02
Journal volume: 114
Paper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://www.sciencedirect.com/science/article/pii/S0300944017305726
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Paper original source: Progress In Organic Coatings. 114 259-267
APA: Guzman, Dailyn; Ramis, Xavier; Fernandez-Francos, Xavier; De la Flor, Silvia; Serra, Angels (2018). Preparation of new biobased materials from a triglycidyl eugenol derivative through thiol-epoxy click reaction. Progress In Organic Coatings, 114(), 259-267. DOI: 10.1016/j.porgcoat.2017.10.025
Article's DOI: 10.1016/j.porgcoat.2017.10.025
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
First page: 259
Publication Type: Journal Publications
Repositori URV