Articles producció científica> Química Analítica i Química Orgànica

Effect of Selected Thiols on Cross-linking of Acrylated Epoxidized Soybean Oil and Properties of Resulting Polymers

  • Identification data

    Identifier: imarina:5132043
    Authors:
    Kasetaite S, De la Flor S, Serra A, Ostrauskaite J.
    Abstract:
    The effect of the chemical structure and functionality of three structurally different thiols on the cross-linking of acrylated epoxidized soybean oil and on the properties of the resulting polymers was investigated in this study. 1,3-Benzenedithiol, pentaerythritol tetra(3-mercaptopropionate), and an hexathiol synthesized from squalene were used in the cross-linking of acrylated epoxidized soybean oil by thiol¿Michael addition reaction. The reactivity of thiols determined from calorimetric curves followed the order: 1,3-benzenedithiol > pentaerythritol tetra(3-mercaptopropionate) > hexathiolated squalene. Thermal and mechanical properties and the swelling in different solvents of the cross-linked polymers were studied. The cross-linked polymer obtained from 1,3-benzenedithiol showed the highest swelling values in chloroform and toluene. The cross-linked polymer with pentaerythritol tetra(3-mercaptopropionate) fragments showed the best mechanical performance (highest mechanical strength and Young¿s modulus) and thermal stability. The cross-linked polymers from hexathiolated squalene showed the highest glass transition temperature.
  • Others:

    Author, as appears in the article.: Kasetaite S, De la Flor S, Serra A, Ostrauskaite J.
    Department: Química Analítica i Química Orgànica Enginyeria Mecànica
    e-ISSN: 2073-4360
    URV's Author/s: De la Flor Lopez, Silvia / Serra Albet, Maria Angels
    Keywords: Thiol–michael Thiol-michael Thiol Thermosets Soybean oil Renewable resources Michael addition Cross-linking Boron nitride Bio-based polymer soybean oil cross-linking bio-based polymer
    Abstract: The effect of the chemical structure and functionality of three structurally different thiols on the cross-linking of acrylated epoxidized soybean oil and on the properties of the resulting polymers was investigated in this study. 1,3-Benzenedithiol, pentaerythritol tetra(3-mercaptopropionate), and an hexathiol synthesized from squalene were used in the cross-linking of acrylated epoxidized soybean oil by thiol¿Michael addition reaction. The reactivity of thiols determined from calorimetric curves followed the order: 1,3-benzenedithiol > pentaerythritol tetra(3-mercaptopropionate) > hexathiolated squalene. Thermal and mechanical properties and the swelling in different solvents of the cross-linked polymers were studied. The cross-linked polymer obtained from 1,3-benzenedithiol showed the highest swelling values in chloroform and toluene. The cross-linked polymer with pentaerythritol tetra(3-mercaptopropionate) fragments showed the best mechanical performance (highest mechanical strength and Young¿s modulus) and thermal stability. The cross-linked polymers from hexathiolated squalene showed the highest glass transition temperature.
    Thematic Areas: Polymers and plastics Polymer science Odontología General chemistry Farmacia Engenharias ii Ciências biológicas ii Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 20734360
    Author's mail: angels.serra@urv.cat silvia.delaflor@urv.cat
    Author identifier: 0000-0003-1387-0358 0000-0002-6851-1371
    Record's date: 2024-09-07
    Journal volume: 10
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://www.mdpi.com/2073-4360/10/4/439
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Polymers. 10 (4):
    APA: Kasetaite S, De la Flor S, Serra A, Ostrauskaite J. (2018). Effect of Selected Thiols on Cross-linking of Acrylated Epoxidized Soybean Oil and Properties of Resulting Polymers. Polymers, 10(4), -. DOI: 10.3390/polym10040439
    Article's DOI: 10.3390/polym10040439
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2018
    First page: 439
    Publication Type: Journal Publications
  • Keywords:

    Chemistry (Miscellaneous),Polymer Science,Polymers and Plastics
    Thiol–michael
    Thiol-michael
    Thiol
    Thermosets
    Soybean oil
    Renewable resources
    Michael addition
    Cross-linking
    Boron nitride
    Bio-based polymer
    soybean oil
    cross-linking
    bio-based polymer
    Polymers and plastics
    Polymer science
    Odontología
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas ii
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Astronomia / física
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