Author, as appears in the article.: Moreno, Adrian; Jezorek, Ryan L.; Liu, Tong; Galia, Marina; Lligadas, Gerard; Percec, Virgil
Department: Química Analítica i Química Orgànica
URV's Author/s: Galià Clua, Marina Teresa / Lligadas Puig, Gerard
Keywords: Hashtag Etiqueta «#» @uroweb @residentesaeu @infoAeu
Abstract: © 2018 The Royal Society of Chemistry. The high bromine chain end functionality of polyacrylates synthesized by single electron transfer living radical polymerization (SET-LRP) mediated by TREN in a biphasic acetone-water mixture containing Cu(ii)Br2 can be exploited to introduce specific functional groups to the chain-ends of these polymers. Here, the α-bromoester end groups of poly(methyl acrylate) (PMA) synthesized in this biphasic SET-LRP system using non-activated Cu(0) wire as catalyst were reacted also under heterogeneous biphasic conditions with potassium acrylate to yield PMA macromonomers and telechelics with α- and α,ω-acrylate chain ends. The reagents used in both steps are air insensitive and inexpensive. 500 MHz 1H NMR, GPC and MALDI-TOF analyses in combination with the thio-bromo click reaction were used to confirm the high efficiency of this two-step protocol. The reactive nature of these macromonomers by the preparation of a PMA-g-PMA more complex architecture was also demonstrated.
Thematic Areas: Química Polymers and plastics Polymer science Organic chemistry Engenharias ii Biomedical engineering Bioengineering Biochemistry
ISSN: 17599954
Author's mail: marina.galia@urv.cat gerard.lligadas@urv.cat
Author identifier: 0000-0002-4359-4510 0000-0002-8519-1840
Last page: 1899
Record's date: 2024-09-07
Journal volume: 9
Papper version: info:eu-repo/semantics/submittedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Polymer Chemistry. 9 (14): 1885-1899
APA: Moreno, Adrian; Jezorek, Ryan L.; Liu, Tong; Galia, Marina; Lligadas, Gerard; Percec, Virgil (2018). Macromonomers, telechelics and more complex architectures of PMA by a combination of biphasic SET-LRP and biphasic esterification. Polymer Chemistry, 9(14), 1885-1899. DOI: 10.1039/c8py00150b
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
First page: 1885
Publication Type: Journal Publications
Repositori URV