Author, as appears in the article.: Konuray O., Areny N., Morancho J., Fernández-Francos X., Serra À., Ramis X.
Department: Química Analítica i Química Orgànica
URV's Author/s: Fernández Francos, Xavier / Serra Albet, Maria Angels
Keywords: Thermosets Polímers amb propietats de memoria de forma Latent catalyst Latent base Epoxy resin Epoxy Dual-curing Diamine
Abstract: A new family of dual-curable poly(hydroxyamine)-poly(ether) thermosets based on off-stoichiometric amine-epoxy formulations has been prepared and characterized. The first curing stage was a self-limiting click epoxy-amine polycondensation with an excess of epoxides and the second stage was an anionic homopolymerization of the unreacted epoxy groups, initiated by a latent base. The curing process was sequential with storage stable intermediate materials. The latency of these partially-cured intermediate materials was established not only by a thermally activated base generator, but also by the vitrification of the formulations. The intermediate and final materials exhibit a wide range of properties depending on the relative contribution of both curing stages. Intermediate materials can either be shape conformable solids, or liquids that are applicable as adhesives. Fully cured materials exhibit shape-memory effect.
Thematic Areas: Química Polymers and plastics Polymer science Organic chemistry Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Biotecnología Astronomia / física
ISSN: 00323861
Author's mail: angels.serra@urv.cat xavier.fernandez@urv.cat
Author identifier: 0000-0003-1387-0358 0000-0002-3492-2922
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0032386118304361
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Polymer. 146 42-52
APA: Konuray O., Areny N., Morancho J., Fernández-Francos X., Serra À., Ramis X. (2018). Preparation and characterization of dual-curable off-stoichiometric amine-epoxy thermosets with latent reactivity. Polymer, 146(), 42-52. DOI: 10.1016/j.polymer.2018.05.040
Article's DOI: 10.1016/j.polymer.2018.05.040
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
Publication Type: Journal Publications
Repositori URV