Articles producció científica> Enginyeria Química

PVDF Membrane Morphology¿Influence of Polymer Molecular Weight and Preparation Temperature

  • Identification data

    Identifier: imarina:5132469
    Authors:
    M. HaponskaA. Trojanowska,A. NogalskaR.JastrzabT. GumiB. Tylkowski
    Abstract:
    In this study, we successfully prepared nine non-woven, supported polyvinylidene fluoride (PVDF) membranes, using a phase inversion precipitation method, starting from a 15 wt % PVDF solution in N-methyl-2-pyrrolidone. Various membrane morphologies were obtained by using (1) PVDF polymers, with diverse molecular weights ranging from 300 to 700 kDa, and (2) different temperature coagulation baths (20, 40, and 60 ± 2 °C) used for the film precipitation. An environmental scanning electron microscope (ESEM) was used for surface and cross-section morphology characterization. An atomic force microscope (AFM) was employed to investigate surface roughness, while a contact angle (CA) instrument was used for membrane hydrophobicity studies. Fourier transform infrared spectroscopy (FTIR) results show that the fabricated membranes are formed by a mixture of TGTG' chains, in α phase crystalline domains, and all-TTTT trans planar zigzag chains characteristic to β phase. Moreover, generated results indicate that the phases' content and membrane morphologies depend on the polymer molecular weight and conditions used for the membranes' preparation. The diversity of fabricated membranes could be applied by the End User Industries for different applications
  • Others:

    Author, as appears in the article.: M. Haponska; A. Trojanowska,;A. Nogalska; R.Jastrzab; T. Gumi; B. Tylkowski
    Department: Enginyeria Química
    e-ISSN: 2073-4360
    URV's Author/s: GUMÍ CABALLERO, TÀNIA / NOGALSKA, ADRIANNA / Tylkowski, Bartosz
    Keywords: Pvdf membrane Polymer molecular weight Coagulation bath temperature pvdf membrane coagulation bath temperature
    Abstract: In this study, we successfully prepared nine non-woven, supported polyvinylidene fluoride (PVDF) membranes, using a phase inversion precipitation method, starting from a 15 wt % PVDF solution in N-methyl-2-pyrrolidone. Various membrane morphologies were obtained by using (1) PVDF polymers, with diverse molecular weights ranging from 300 to 700 kDa, and (2) different temperature coagulation baths (20, 40, and 60 ± 2 °C) used for the film precipitation. An environmental scanning electron microscope (ESEM) was used for surface and cross-section morphology characterization. An atomic force microscope (AFM) was employed to investigate surface roughness, while a contact angle (CA) instrument was used for membrane hydrophobicity studies. Fourier transform infrared spectroscopy (FTIR) results show that the fabricated membranes are formed by a mixture of TGTG' chains, in α phase crystalline domains, and all-TTTT trans planar zigzag chains characteristic to β phase. Moreover, generated results indicate that the phases' content and membrane morphologies depend on the polymer molecular weight and conditions used for the membranes' preparation. The diversity of fabricated membranes could be applied by the End User Industries for different applications
    Thematic Areas: Polymers and plastics Polymer science Odontología General chemistry Farmacia Engenharias ii Ciências biológicas ii Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 20734360
    Author's mail: bartosz.tylkowski@urv.cat
    Author identifier: 0000-0002-4163-0178
    Record's date: 2024-09-07
    Journal volume: 9
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://www.mdpi.com/2073-4360/9/12/718
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Polymers. 9 (12): 718-731
    APA: M. Haponska; A. Trojanowska,;A. Nogalska; R.Jastrzab; T. Gumi; B. Tylkowski (2017). PVDF Membrane Morphology¿Influence of Polymer Molecular Weight and Preparation Temperature. Polymers, 9(12), 718-731. DOI: 10.3390/polym9120718
    Article's DOI: 10.3390/polym9120718
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    Publication Type: Journal Publications
  • Keywords:

    Chemistry (Miscellaneous),Polymer Science,Polymers and Plastics
    Pvdf membrane
    Polymer molecular weight
    Coagulation bath temperature
    pvdf membrane
    coagulation bath temperature
    Polymers and plastics
    Polymer science
    Odontología
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas ii
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Astronomia / física
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