Author, as appears in the article.: Moreno A, Galià M, Lligadas G, Percec V.
Department: Química Analítica i Química Orgànica
URV's Author/s: Galià Clua, Marina Teresa / Lligadas Puig, Gerard
Keywords: Clean water and sanitation
Abstract: The fluorinated alcohol 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) is an especially effective solvent for solubilizing a wide range of polymers. However, the performance of HFIP as SET-LRP solvent has classically been questioned due to its poor Cu(I)X disproportionating properties. Taking advantage of the fast and quantitative disproportionation of Cu(I)X in water, SET-LRP in organic solvent/water mixtures rids the organic solvent of mediating this fundamental event. Here, the Cu(0) wire-catalyzed SET-LRP synthesis of well-defined poly(methyl acrylate)s and poly(butyl acrylate)s with narrow molecular weight distribution and near perfect bromine chain end functionality is reported in HFIP/water mixtures. The results reported here support the potential of HFIP/water mixtures in the preparation of more complex architectures including polymers with dual control over molecular weight and tacticity. Since HFIP is also a classic solvent for the denaturation of proteins this SET-LRP system is also expected to find applications in the grafting of protein.
Thematic Areas: Química Polymers and plastics Polymer science Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, organic Biotecnología Biomaterials Bioengineering Biochemistry & molecular biology Astronomia / física
ISSN: 15257797
Author's mail: marina.galia@urv.cat gerard.lligadas@urv.cat
Author identifier: 0000-0002-4359-4510 0000-0002-8519-1840
Last page: 4491
Record's date: 2024-11-16
Journal volume: 19
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/acs.biomac.8b01381
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Biomacromolecules. 19 (11): 4480-4491
APA: Moreno A, Galià M, Lligadas G, Percec V. (2018). SET-LRP in Biphasic Mixtures of the Nondisproportionating Solvent Hexafluoroisopropanol with Water. Biomacromolecules, 19(11), 4480-4491. DOI: 10.1021/acs.biomac.8b01381
Article's DOI: 10.1021/acs.biomac.8b01381
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
First page: 4480
Publication Type: Journal Publications
Repositori URV