Articles producció científicaQuímica Analítica i Química Orgànica

Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands

  • Identification data

    Identifier:  imarina:5874630
    Handle: https://hdl.handle.net/20.500.11797/imarina5874630
    Authors:  Delgado-Rebollo, M; García-Morales, C; Maya, C; Prieto, A; Echavarren, AM; Pérez, PJ
    Abstract:
    The synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies. (C) 2019 Elsevier B.V. All rights reserved.

  • Others:

    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0022328X19302906?via%3Dihub
    APA: Delgado-Rebollo, M; García-Morales, C; Maya, C; Prieto, A; Echavarren, AM; Pérez, PJ (2019). Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands. Journal Of Organometallic Chemistry, 898(UNSP 120856), 120856-. DOI: 10.1016/j.jorganchem.2019.07.007
    Paper original source: Journal Of Organometallic Chemistry. 898 (UNSP 120856): 120856-
    Article's DOI: 10.1016/j.jorganchem.2019.07.007
    Journal publication year: 2019-10-15
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2026-05-09
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    ISSN: 0022328X
    Author, as appears in the article.: Delgado-Rebollo, M; García-Morales, C; Maya, C; Prieto, A; Echavarren, AM; Pérez, PJ
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, Materials chemistry, Inorganic chemistry, Engenharias ii, Ciências agrárias i, Chemistry, organic, Chemistry, inorganic & nuclear, Biochemistry, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Keywords:

    Structural-characterization
    Silver(i)
    Silver carbene
    Olefin metathesis
    Neutral and cationic complexes
    Gold carbene
    Fluorinated n-heterocyclic carbenes
    Copper carbene
    Catalysts
    Biochemistry
    Chemistry
    Inorganic & Nuclear
    Organic
    Inorganic Chemistry
    Materials Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Engenharias ii
    Ciências agrárias i
    Astronomia / física

  • Documents:

    DocumentPrincipal

  • Cerca a google

    Search to google scholar