Articles producció científica> Química Analítica i Química Orgànica

Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands

  • Identification data

    Identifier: imarina:5874630
    Authors:
    Delgado-Rebollo, ManuelaGarcia-Morales, CristinaMaya, CeliaPrieto, AuxiliadoraEchavarren, Antonio M.Perez, Pedro J.
    Abstract:
    The synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies. (C) 2019 Elsevier B.V. All rights reserved.
  • Others:

    Author, as appears in the article.: Delgado-Rebollo, Manuela; Garcia-Morales, Cristina; Maya, Celia; Prieto, Auxiliadora; Echavarren, Antonio M.; Perez, Pedro J.;
    Department: Química Analítica i Química Orgànica
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Keywords: Structural-characterization Silver(i) Silver carbene Olefin metathesis Neutral and cationic complexes Gold carbene Fluorinated n-heterocyclic carbenes Copper carbene Catalysts
    Abstract: The synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies. (C) 2019 Elsevier B.V. All rights reserved.
    Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Materials chemistry Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias ii Ciências biológicas ii Ciências agrárias i Chemistry, organic Chemistry, inorganic & nuclear Biochemistry Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0022328X
    Author's mail: antoniomaria.echavarren@urv.cat
    Author identifier: 0000-0002-6418-7930
    Record's date: 2022-07-23
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0022328X19302906?via%3Dihub
    Papper original source: Journal Of Organometallic Chemistry. 898 (UNSP 120856):
    APA: Delgado-Rebollo, Manuela; Garcia-Morales, Cristina; Maya, Celia; Prieto, Auxiliadora; Echavarren, Antonio M.; Perez, Pedro J.; (2019). Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands. Journal Of Organometallic Chemistry, 898(UNSP 120856), -. DOI: 10.1016/j.jorganchem.2019.07.007
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1016/j.jorganchem.2019.07.007
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2019
    Publication Type: Journal Publications
  • Keywords:

    Biochemistry,Chemistry, Inorganic & Nuclear,Chemistry, Organic,Inorganic Chemistry,Materials Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Structural-characterization
    Silver(i)
    Silver carbene
    Olefin metathesis
    Neutral and cationic complexes
    Gold carbene
    Fluorinated n-heterocyclic carbenes
    Copper carbene
    Catalysts
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Materials chemistry
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas ii
    Ciências agrárias i
    Chemistry, organic
    Chemistry, inorganic & nuclear
    Biochemistry
    Astronomia / física
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