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Buchwald-Type Ligands on Gold(I) Catalysis

  • Identification data

    Identifier: imarina:6138918
    Authors:
    Zuccarello, GiuseppeZanini, MargheritaEchavarren, Antonio M.
    Abstract:
    Dialkyl biarylphosphine ligands, presented in the context of Pd-catalyzed cross-coupling reactions, have been extensively applied in gold(I) catalysis giving rise to numerous transformations and reaction pathways otherwise inaccessible under the action of other gold(I) catalysts. This review emphasizes how this privileged ligand class, as well as recent modifications on the biarylphosphine motive, have triggered the discovery of new reactivities in our research program. Finally, the introduction of chiral information on the ligand scaffold provides new solutions to challenging gold(I)-catalyzed enantioselective transformations.
  • Others:

    Author, as appears in the article.: Zuccarello, Giuseppe; Zanini, Margherita; Echavarren, Antonio M.;
    Department: Química Analítica i Química Orgànica
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO / Zanini, Margherita
    Keywords: Retro-buchner reaction Platinum Gold(i) catalysis Cyclizations Cyclization Complexes Carbenes Biarylphosphines Asymmetric catalysis Amination Alkynes Activated ketones A-c 1,6-enynes
    Abstract: Dialkyl biarylphosphine ligands, presented in the context of Pd-catalyzed cross-coupling reactions, have been extensively applied in gold(I) catalysis giving rise to numerous transformations and reaction pathways otherwise inaccessible under the action of other gold(I) catalysts. This review emphasizes how this privileged ligand class, as well as recent modifications on the biarylphosphine motive, have triggered the discovery of new reactivities in our research program. Finally, the introduction of chiral information on the ligand scaffold provides new solutions to challenging gold(I)-catalyzed enantioselective transformations.
    Thematic Areas: Materiais General chemistry Ensino Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: antoniomaria.echavarren@urv.cat
    Author identifier: 0000-0002-6418-7930
    Record's date: 2024-01-13
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/ijch.201900179
    Papper original source: Israel Journal Of Chemistry. 60 (3-4): 360-372
    APA: Zuccarello, Giuseppe; Zanini, Margherita; Echavarren, Antonio M.; (2020). Buchwald-Type Ligands on Gold(I) Catalysis. Israel Journal Of Chemistry, 60(3-4), 360-372. DOI: 10.1002/ijch.201900179
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1002/ijch.201900179
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2020
    Publication Type: Journal Publications
  • Keywords:

    Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Retro-buchner reaction
    Platinum
    Gold(i) catalysis
    Cyclizations
    Cyclization
    Complexes
    Carbenes
    Biarylphosphines
    Asymmetric catalysis
    Amination
    Alkynes
    Activated ketones
    A-c
    1,6-enynes
    Materiais
    General chemistry
    Ensino
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Astronomia / física
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