Author, as appears in the article.: Zuccarello, Giuseppe; Zanini, Margherita; Echavarren, Antonio M.;
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO / Zanini, Margherita
Keywords: Retro-buchner reaction Platinum Gold(i) catalysis Cyclizations Cyclization Complexes Carbenes Biarylphosphines Asymmetric catalysis Amination Alkynes Activated ketones A-c 1,6-enynes
Abstract: Dialkyl biarylphosphine ligands, presented in the context of Pd-catalyzed cross-coupling reactions, have been extensively applied in gold(I) catalysis giving rise to numerous transformations and reaction pathways otherwise inaccessible under the action of other gold(I) catalysts. This review emphasizes how this privileged ligand class, as well as recent modifications on the biarylphosphine motive, have triggered the discovery of new reactivities in our research program. Finally, the introduction of chiral information on the ligand scaffold provides new solutions to challenging gold(I)-catalyzed enantioselective transformations.
Thematic Areas: Materiais General chemistry Ensino Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: antoniomaria.echavarren@urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2024-01-13
Papper version: info:eu-repo/semantics/publishedVersion
Papper original source: Israel Journal Of Chemistry. 60 (3-4): 360-372
APA: Zuccarello, Giuseppe; Zanini, Margherita; Echavarren, Antonio M.; (2020). Buchwald-Type Ligands on Gold(I) Catalysis. Israel Journal Of Chemistry, 60(3-4), 360-372. DOI: 10.1002/ijch.201900179
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2020
Publication Type: Journal Publications
Repositori URV